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Chemical Bonds Section 2.3
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Learning Objectives Identify if a bond is covalent, ionic, or a hydrogen bond. Explain how each type of bond forms & put them in order of increasing or decreasing strength. Distinguish between polar and nonpolar molecules.
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Atoms Are Held Together By Bonds
Chemical bonds are what hold atoms in a molecule together Ex. Ionic, Covalent, and Hydrogen bonds Bond energy = the energy needed to break a chemical bond Electronegativity = a measure of how much an atom wants electrons
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Covalent Bonds The SHARING of electrons
Each atom wants an octet in their valence shell
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Chlorine forms a covalent bond with itself Cl2
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How will two chlorine atoms react? Cl Cl
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Cl Cl Each chlorine atom wants to
gain one electron to achieve an octet
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Cl Cl do to achieve an octet? What’s the solution – what can they
Neither atom will give up an electron – chlorine is highly electronegative. What’s the solution – what can they do to achieve an octet?
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Cl Cl
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Cl Cl
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Cl Cl
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Cl Cl
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Cl Cl octet
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Cl Cl octet
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Cl Cl The octet is achieved by each atom sharing the
electron pair in the middle
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Cl Cl The octet is achieved by each atom sharing the
electron pair in the middle
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Cl Cl This is the bonding pair
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Cl Cl It is a single bonding pair
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Cl Cl It is called a SINGLE BOND
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Single bonds are abbreviated
Cl Cl Single bonds are abbreviated with a dash
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This is the chlorine molecule,
Cl Cl This is the chlorine molecule, Cl2
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O2 Oxygen is also one of the diatomic molecules
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O How will two oxygen atoms bond?
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O Each atom has two unpaired electrons
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O
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O
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O
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O
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O
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O
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O Oxygen atoms are highly electronegative.
So both atoms want to gain two electrons.
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O Oxygen atoms are highly electronegative.
So both atoms want to gain two electrons.
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O
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O O
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O O
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O O
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Both electron pairs are shared.
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O O 6 valence electrons plus 2 shared electrons = full octet
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O O 6 valence electrons plus 2 shared electrons = full octet
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O O two bonding pairs, making a double bond
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O O = For convenience, the double bond can be shown as two dashes.
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This is the oxygen molecule,
= this is so cool!! This is the oxygen molecule, O2
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Two Types of Covalent Bonds
Polar = electrons are shared UNEQUALLY One atom is more electronegative than the other atoms & pulls the electrons towards its atomic nucleus A partial positive area & a partial negative area is created Example – Water (H2O)
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Nonpolar = electrons are shared EQUALLY
All atoms have similar electronegativities The molecule has no charge
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Ionic Bonds The TRANSFER of electrons
Electrons are moved from one atom to another atom to achieve a full valence shell
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Ionic Bonding Creates Ions
Ion = an atom with a positive or negative charge due to having unequal numbers of protons & electrons Cation = ion with a positive (+) charge Anion = ion with a negative (-) charge
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Ions are attracted to each other because of their opposite charges
Just like a magnet Ionic compounds easily dissociate (separate) in water
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Hydrogen Bonds Partial positive charge of a hydrogen is attracted to the partial negative charge of another polar molecule Weak by themselves Strong together Easily formed & broken
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Solutions Solvent = does the dissolving Solute = is dissolved
The liquid part Water is an excellent solvent because the polar ends surround ions of the opposite charge Prevents ions from bonding back together Solute = is dissolved The solid
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