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What is the role of electronegativity?
Bonding What is the role of electronegativity?
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Nuclei can pull on another atom’s electrons.
Nuclei in a tug of war Nuclei can pull on another atom’s electrons.
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Character determined by difference in electronegativities.
Bond character Bonds are on a sliding scale from nonpolar covalent to ionic.
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Equal electronegativity values = equal pull on the electrons
Nuclei in a tug of war Nonpolar covalent bonds
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Unequal electronegativity values = unequal pull on the electrons
Nuclei in a tug of war Polar covalent bonds
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Hugely unequal electronegativity values = essentially a transfer of electrons
Nuclei in a tug of war Ionic bonds
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Electron densities Bond character Note the equal, unequal and hugely unequal sharing of eletrons.
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