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Esters
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Esters Esters are formed by the reaction of a carboxylic acid with an alcohol e.g. CH3COOH CH3OH = CH3COOCH H2O Ethanoic acid Methanol Methyl ethanoate
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Naming esters: methyl ethanoate
The first part of the ester name comes from the parent alcohol with the - anol changed to – yl and the second part of the name comes from the parent acid with the - oic acid changed to – oate.
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Methyl methanoate HCOOCH3
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Ethyl methanoate HCOOC2H5
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Methyl ethanoate CH3COOCH3
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Ethyl ethanoate CH3COOC2H5
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Physical properties Physical state: Liquid
Boiling points higher than the corresponding alkanes, but lower than the corresponding alcohols
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Physical properties Soluble in water and non-polar solvents such as cyclohexane As the number of carbon atoms in a molecule of the ester increases, solubility in water decreases, while solubility in cyclohexane increases
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Occurrence and uses of esters
Occur naturally in fruits – are responsible for their flavours - and flowers – are responsible for their pleasant smells Fats and oils are naturally occurring esters of long chain carboxylic acids Ethyl ethanoate is used as a solvent for printing inks and paints
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