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pH and Acid-Base Indicators
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The pH Scale “The power of hydrogen” Expresses the concentration of H+
Acidic Neutral Basic [H+] > [OH-] [H+] = [OH-] [H+] < [OH-]
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H2O(l) H+(aq) + OH-(aq)
Ionization of Water Pure water is neutral (pH 7) Why? You might think that pure water contains no H+ or OH- However, even pure water ionizes slightly At SATP, ~2 in every billion water molecules ionize: H2O(l) H+(aq) + OH-(aq) i.e [H+] in pure water is ~ 1.0 X 10-7 mol/L
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Relating [H+] to pH [H+] = 10-pH pH = -log[H+] Acidic Neutral Basic
[H+] > 1.0 X 10-7 M pH < 7 i.e. 1.0 X 10-6 M 1.0 X 10-2 M [H+] = 1.0 X 10-7 M pH = 7 [H+] < 1.0 X 10-7 M pH > 7 i.e. 1.0 X 10-8 M 1.0 X M pH = -log[H+]
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Acid-Base Indicators A common method for determining pH of a solution is to use an indicator Indicators respond to changes in [H+] (change colour) Universal Indicator Litmus Paper Cabbage Juice
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Bromothymol blue Phenolphthalein
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Homework P. 371 #2-6 P. 371 #9,10 P. 375 #1-4,6cd,12
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Bromothymol blue Universal Indicator
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