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Metallurgy
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Basic Extraction Procedure
Mining Pretreating Magnetic Attraction Cyclone Separation Flotation Leaching Mineral to Compound Pyrometallurgy Hydrometallurgy Compound to Metal Smelting, etc. Electrochemistry Refining Electrorefining Distillation Zone Refining Alloying
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Smelting Wool or Smithsonite = Zinc Carbonate Cow Dung
Hemimorphite = Zinc Silicate Calamine + Oxygen Zinc Oxide Calamine Zinc Oxide + Carbon Monoxide Zinc
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Pyrometallurgy Roasting Calcination
… is a thermal treatment that causes chemical reactions between the ore and the furnace atmosphere. Roasting may lead to oxidation or reduction and may be accompanied by calcination. 2 ZnS(s) O2(g) 2 ZnO(s) SO2(g) 2 MoS2(s) O2(g) 2 MoO3(s) SO2(g) Calcination … is the heating of an ore to bring about its decomposition and the elimination of a volatile product. PbCO3(s) PbO(s) + CO2(g)
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Smelting … is a melting process in which the materials formed in the course of chemical reactions separate into two or more layers. Smelting often involves a roasting stage in the same furnace. Two of the important types of layers formed in smelters are molten metal and slag. The molten metal may consist almost entirely of a single metal, or it may be a solution of two or more metals. Slag consists mainly of molten silicate minerals, with aluminates, phosphates, fluorides, and other ionic compounds as constituents. ZnO(s) + CO(g) Zn(s) + CO2(g)
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