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Ionic Compounds: Naming
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Naming Binary Ionic Compounds
Always name metal (the cation/+ ion) first 2. Write stem of nonmetal (the anion/ - ion) 3. Add ending “ide” to nonmetal Binary = only 2 types of elements (two capital letters)
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Stems of nonmetals Iod Brom Chlor Fluor Hydr is the stem for H Tellur
Selen Arsen Sulf Phosph Ox Nitr
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Metals with one oxidation state
CaO BaS AlN LiCl Al2Se3 Na2O K3N MgF2 Calcium Oxide Barium Sulfide Aluminum Nitride Lithium Chloride Aluminum Selenide Sodium Oxide Potassium Nitride Magnesium Fluoride
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The First Step in Naming
Find metal on PT If metal has only one oxidation state it’s easy If metal has more than one oxidation state, there’s an extra step
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Metals with > 1 oxidation state
Use formula to figure out which oxidation state metal ion has Ex: Fe can be Fe+2 or Fe+3 Name FeO and Fe2O3
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FeO Name: Iron (II) oxide (roman numeral II = charge on Fe)
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Fe2O3 Name: Iron (III) oxide (roman numeral III = charge on Fe)
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Name the following TiCl3 MnO2 AuCl3 MnO Titanium (III) chloride
Manganese (IV) oxide Gold (III) chloride Molybdenum (III) nitride
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Naming compounds with polyatomics
If it contains a polyatomic, same rule, just write the name polyatomic ion (Table E)
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Name the following NaOH LiNO3 Al(NO3)3 Fe(OH)2 Sodium hydroxide
Lithium nitrate Aluminum nitrate Iron (II) hydroxide
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