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Phase Changes
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Names Evaporation / Condensation Melting / Freezing
Sublimation / Deposition Endothermic / Exothermic
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Heat of Vaporization The energy required to vaporize 1 mol of liquid at 1 atm pressure Same as enthalpy of vaporization Varies according to intermolecular forces
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Vapor Pressure The pressure of the vapor present at equilibrium
Varies with temperature Varies with intermolecular attraction
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Figure 10.38: Behavior of a liquid in a closed container.
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Figure 10.40: The three liquids have quite different vapor pressures.
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As temperature increases, more molecules have enough kinetic energy to become a gas.
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Heating Curves Show the temperature changes as heat is added at a constant rate Levels off at places where phase changes because heat is being used to change phase and not to change temperature
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Heat of Fusion Heat released when a substance changes from a liquid to a solid Same thing as enthalpy of fusion
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Heating Curves Heat of vaporization keeps temp. constant
Heat of fusion keeps temp. constant
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Figure 10.49: The phase diagram for water.
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Figure 10.52: The phase diagram for carbon dioxide.
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