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States of Matter Fluids Behavior of Gases
Chapter 3- States Of Matter States of Matter Fluids Behavior of Gases
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Kinetic Molecular Theory
KMT All mater is made of atoms and molecules that act like partilces Particles of matter are always in motion. The kinetic energy (speed) of these particles increases as temperature increases.
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B. Four States of Matter Solids
low KE - particles vibrate but can’t move around definite shape & volume crystalline - repeating geometric pattern amorphous - no pattern (e.g. glass, wax)
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B. Four States of Matter Liquids
higher KE - particles can move around but are still close together indefinite shape definite volume
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B. Four States of Matter Gases
high KE - particles can separate and move throughout container indefinite shape & volume
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B. Four States of Matter Plasma
very high KE - particles collide with enough energy to break into charged particles (+/-) gas-like, indefinite shape & volume Conduct electric current stars, fluorescent light bulbs, TV tubes
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C. Thermal Expansion Most matter expands when heated & contracts when cooled. Total thermal energy= total kinetic energy Temp causes KE. Particles collide with more force & spread out. Thermal energy also depends on # of particles in substance
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melting point = freezing point
Phase Changes Melting solid to liquid Freezing liquid to solid melting point = freezing point
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Phase Changes Vaporization (boiling)
liquid to gas at the boiling point Evaporation liquid to gas below the boiling point Condensation gas to liquid
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Phase Changes Sublimation solid to gas
EX: dry ice, freeze drying, iodine
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Phase Changes
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Conservation of Mass and Energy
When water boils, # of molecules stays the same even as the liquid water loses volume. The mass of steam is the same of the mass of evaporated water Mass cannot be created or destroyed; it can be transformed
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Fluids Fluids= states of matter that have the ability to flow (ones without definite volume) Liquids and Gases are Fluids
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Fluids and Pressure What kind of fluids can you think of related to pressure? Blood pressure, air pressure, water pressure Fluids exert pressure evenly in all directions Pressure is the amount of force per unit area Pressure=Force/Area SI Unit = Pascal
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Buoyancy Force of a fluid that pushes up on an object.
Makes the object seem lighter Why most of your toys didn’t sink in the bathtub
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Properties of Fluids How does a ship float?
Buoyancy – the ability of a fluid to exert an upward force on an object immersed in it.
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Archimedes Principle There are 2 ways objects can float:
1) If the buoyant force on an object is equal to the weight of the fluid displaced by the object. 2) If the density of the object is less than the density of the liquid. What is the density of water? 1 g/ml Will gasoline, with a density of 0.7 g/ml float or sink in water? It will float!
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Archimedes’ Principle
Found that the buoyant force equals the weight of the fluid displaced by an object In other words…the weight of the fluid that has been pushed out of the way
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Why do Ships Float If the weight of the water displaced is less than the weight of the object, the object will sink Otherwise the object will float, with the weight of the water displaced equal to the weight of the object. Archimedes' Principle explains why steel ships float. Steel is more dense than water, so why do ships float?
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Example An object weighs 20N. It displaces a volume that weighs 15N. What is the buoyant force on the object? Will the Object float or sink? Buoyant force=weight of water displaced Buoyant force=15N Object will sink because its weight is greater than the buoyant force acting on it
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Pascal’s Principle Pascal’s Principle: The pressure applied to a fluid is transmitted throughout the fluid Example: When you squeeze one end of toothpaste, toothpaste emerges from the other end. Viscosity: Resistance of a fluid to flow Water vs. Syrup What happens to viscosity if you increase temperature?
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Fluid Flow Viscosity A resistance to flow by a fluid
Water has a low viscosity; it can flow easily Corn syrup has a high viscosity; it flows slowly Temperature affects the viscosity of a fluid Heated items flow faster Colder items flow slower
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Bernoulli’s Principle
Bernoulli’s Principle: As the velocity (speed) of a fluid increases, the pressure exerted by the fluid decreases. Example: Airplanes, Birds Frisbees
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Demonstrating Bernoulli’s Principle
Take your piece of paper and blow on the top of the paper. What happened to your paper? It lifted up This demonstrates Bernoulli’s principle because the velocity of the air you blew over the paper was greater than that of the quiet air below it, which caused the pressure pushing down on the paper lower then the pressure pushing up on the paper V P = V P
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How Airplanes Use Bernoulli’s Principle
As a plane is moving forward the air passing over the wing has a higher velocity then the air below the wing, more pressure pushing up on the wing the pushing down This causes a plane to fly
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Gases
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Properties of Gases No definite shape or volume
Gas particles move rapidly in all directions Gas molecules are in constant motion and frequently collide with one another and their container Gases have a very low density because particles are so far apart Gases are compressible Gases spread out easily and mix with one another. Gases are mostly empty space
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Gases Gases exert pressure on their containers
Gases will try to escape containers when possible Let’s look at a balloon… When the internal pressure inside the balloon became to great, it popped!
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Gas Laws For temperature values with gas laws…we have to use Kelvin instead of degrees Celsius 0ºC= K Ex. Find the temperature in units of Kelvin if it is at 25ºC =298.15K
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The Gas Laws Boyle’s Law P V Relates pressure and volume
For a fixed amount of gas at constant temperature, volume increases as pressure decreases As volume decreases, pressure increases Inversely Related
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Gas Laws Charles’ Law Relates temperature to volume
For a fixed amount of gas at a constant pressure, as volume increases temperature increases As volume decreases, temperature decreases Directly related V T
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Gas Laws Gay-Lussac’s Law Relates pressure to temperature
For a fixed amount of gas at constant volume, as pressure increases temperature increases As temperature decreases, pressure decreases Directly related P T
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Gas Law Problems BOYLE’S LAW P V
A gas occupies 100 mL at 150 kPa. Find its volume at 200 kPa. BOYLE’S LAW GIVEN: V1 = 100. mL P1 = 150. kPa V2 = ? P2 = 200. kPa P V WORK: P1V1T2 = P2V2T1 (150.kPa)(100.mL)=(200.kPa)V2 V2 = 75.0 mL C. Johannesson
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Gas Law Problems CHARLES’ LAW T V
A gas occupies 473 cm3 at 36°C. Find its volume at 94°C. CHARLES’ LAW GIVEN: V1 = 473 cm3 T1 = 36°C = 309K V2 = ? T2 = 94°C = 367K T V WORK: P1V1T2 = P2V2T1 (473 cm3)(367 K)=V2(309 K) V2 = 562 cm3 C. Johannesson
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