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Radioactivity
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History Henri Becquerel discovered radioactivity.
Left uranium salts in the dark on photographic paper and found that a reaction had occurred – could only have occurred naturally. Won Nobel Prize in physics for it
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Pierre & Marie Curie discovered a number of radioactive elements – polonium, germanium & radium
Marie won the Nobel Prize in chemistry for these discoveries Pierre died before he could be awarded
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Radioactivity Radioactivity is the spontaneous breaking up of unstable nuclei with the emission of one or more types of radiation Lots of natural radiation around us – called background radiation Main source of background radiation in Ireland is from radon gas
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Radioactive particles
3 types – alpha, beta & gamma Alpha: 2 protons & 2 neutrons stuck together like a helium (He) nucleus Positive charge Low penetrating power Stopped by sheet of paper E.g., americium-241 used in smoke detectors
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Beta: Neutron converted into a proton and an electron
Proton stays in nucleus and electron is emitted Negative charge More penetrating than alpha Stopped by sheet of aluminium foil E.g., carbon-14 used in carbon dating by archaeologists
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Gamma: high energy electromagnetic rays No charge Most penetrating
Stopped by thick slab of lead E.g., cobalt-60 used to kill cancer cells in radiotherapy treatment for cancer
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Detection Geiger-Muller tube connected to a ratemeter
Switch it on and note the background radiation count Using a tongs hold a radioactive sample up to the tube and note that the count rate increases
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Place a suitable source for blocking the sample between it and the tube and note that the count rate falls Repeat for different samples
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Nuclear reactions In a chemical reaction bonds are broken and new ones are formed In a nuclear reaction radioactive radiation is emitted from a nucleus and a new element is formed
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Emission of alpha particles:
Nucleus loses 2 protons and 2 neutrons Mass number AND Atomic number decrease New element formed Po → _____ He
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Emission of beta particles: - Nucleus loses a neutron but gains a
proton so mass number stays the same - Atomic number increases - New element formed Na → _____ e Bi → _____ e
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Emission of gamma energy:
Energy is lost from the nucleus but no new element is formed Usually accompanies emission of other radioactive particles Changing of one element to another is called transmutation.
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Radioisotopes & their uses
Radioactive isotopes are called radioisotopes Uses: Medical: Gamma rays used in cancer treatment to kill cancer cells. Gamma rays used to sterilise equipment.
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Archaeological: Carbon 14 dating used to age substances Carbon consists of three isotopes, carbon-14 being radioactive By comparing the ratio of radioactive to non-radioactive isotopes can calculate age
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Agricultural: Radioactive isotopes added to fertilisers to measure the uptake of the fertiliser Farmers can measure amount of radioactivity in leaves of plants to see how far the fertiliser has travelled in the plant
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Food irradiation: Gamma rays sterilise food by killing off bacteria and mould which can spoil it Not suitable for all foods, e.g., causes red meat to change colour and taste
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Industrial: Test for leaks in pipes
Radioactive isotope added and followed until it can no longer be registered on Geiger-Muller counter Spot where signal disappears is spot where leak is in pipe.
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Half-life Half-life of a radioactive element is the time taken for half the nuclei in a sample to decay Use Geiger-Muller tube and ratemeter to measure it
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Examples – - Carbon-14 = 5,700 yrs - Cobalt-60 = 5 yrs - Polonium-234 = s
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Half-life graph
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