1. Alcohol & Halide Properties

2. BPs increase as substitutions increase
Boiling Points
BPs increase as substitutions increase

3. CH4 BP = -161 oC
CH3Cl BP = -24 oC
CH2Cl2 BP = 40 oC
CHCl3 BP = 61 oC
CCl4 BP = 74 oC

4. Alcohol BPs greater than halide BPs
Boiling Points
Alcohol BPs greater than halide BPs

5. CH3OH BP = 65 oC CH3CH2OH BP = 78 oC CH3CH2CH2OH BP = 97 oC

6. CH3Cl BP = -64 oC CH3CH2Cl BP = 13 oC CH3CH2CH2Cl BP = 47 oC

7. How much of one substance will dissolve in another
Solubility
How much of one substance will dissolve in another

8. General hydrocarbons are non-polar & insoluble in H2O
Solubility
General hydrocarbons are non-polar & insoluble in H2O

9. Halides & alcohols increase the solubility of organic cmpds in H2O

10. Similarly placed alcohols affect solubility more than halides

11. Ethers slightly increase the solubility of organic cmpds in water

12. Location of the ether is important in solubility

13. Solubility & BP Trends OH OH OH

14. Trends

15. Trends OH O

16. Drill: Draw & Name Organic Reactants & Major Products
2-methylhexa-2-ene + HCl