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Chemical Nomenclature
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Basic Types of Compounds
Ionic compound Binary ionic Polyatomic cation/anion Transition metals Molecular compounds Binary molecular Acid/Base compounds Binary acids Oxyacids
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Ionic Compounds Cations – named first in compound
Name as written on periodic table Group 1A -3A Metals + charge K+, Ca2+, Al3+ Name the above Transition Metals – named with roman number to represent charge Fe3+, Cu2+, Cr2+ Name the above (be careful!!)
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Ionic Compounds (cont)
Anions Non-metals ‘-’ charge Group 4A-7A Name element as is with ending of –ide Example – O-2 oxygen oxide Br -, C -4, S-2 Name the above
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Ionic and covalent compounds
Polyatomic ions Combination of covalently bonding elements Combine with metal or nonmetal element or another polyatomic ion + polyatomic ion NH4+ - polyatomic ions Many – remember polyatomic ion sheet Name polyatomic ions as is – DO NOT CHANGE THEIR NAME
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Common Polyatomic Ions
..\..\All Classes\Polyatomic Ion List.doc ..\..\All Classes\COMMON POLYATOMIC IONS.doc
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Practice NH4NO3 Al(NO3)3 Mg3(PO4)2
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Ionic Compounds (cont)
Transition metals Groups 3-12 Name of metal + (roman numeral) Roman numeral Charge of metal Determine charge from non-metal and subscripts Example CrO Chromium (II) oxide Oxygen charge -2 Name the following PbS, MnO2, Co2O3
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Molecular Compounds Combination of two or more nonmetals or highly electronegative elements or group of elements Electrons are shared Types Binary molecular compound Polyatomic compound Acid/Base compound
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Binary Covalently Bonded Compounds
1 Mono 2 Di 3 Tri 4 Tetra 5 Penta 6 Hexa 7 Hepta 8 Octa 9 Nona 10 Deca Use of prefixes
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Molecular Compounds 2 non-metals
Name 1st non-metal as is Name 2nd non-metal with –ide ending Prefixes indicate # of atoms of each element Example P2O5 Diphosphorus pentoxide Name the following CO2 , SO3 , XeF6 , N2O
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Molecular Compounds Examples NH3 ammonia
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hydrates
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Single bonded carbon and hydrogen compounds
Organic Compounds Meth- C Eth- C2 Prop- C3 But- C4 Pent- C5 Hex- C6 Hept- C7 Oct- C8 Non- C9 Dec- C10 Single bonded carbon and hydrogen compounds
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Organic Compounds Single bonded ending Single bonded Double bonded
-ane Ex: CH4 Methane Double bonded -ene Triple bonded -yne Single bonded CnH2n+2 Double bonded CnH2n Triple bonded CnHn
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Examples
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Acids and Bases Acids Binary Acids Hydrogen and one other element
H hydro Name other element ending –ic followed by acid Example HCl Hydrochloric acid
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Acids/Bases (cont) Oxyacids
Acids containing oxyanion – a polyatomic ion containing oxygen Pay attention to ending of polyatomic ion Ending –ate -ic acid -ite -ous acid Examples HNO3 nitric acid Name the following H3 PO4 , HF, HClO3 , HClO2 , H2S
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Common Acids
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Bases No special naming rules Most end in –OH group Exception
Name this polyatomic ion – Exception NH3 Organic bases non covered except in lab
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