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Covalent bonding AH Chemistry Unit 1(b)
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Potential energy diagram
Bond dissociation energy Bond length (distance between nuclei at minimum energy)
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Lewis formulae
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Dative covalent bonds Co-ordinate covalent bonds
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Writing Lewis formulae
Calculate total valence electrons – for ions, add or subtract electrons accordingly Write skeleton structure – more electronegative atoms usually surround central atom Distribute electrons to atoms surrounding central atom Distribute remaining electrons to central atom
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Examples SCl2 COCl2 BF4-
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Resonance structures Represents delocalised bonding
You describe the electron structure of a molecule having delocalised bonding by writing all possible electron-dot formulae
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Ozone
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Sulphur dioxide
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Carbonate ion
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Exceptions to the octet rule
BCl3 PCl5
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