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Specific and Latent Heat
Definitions Heat and Temperature Change Examples Heat and Phase Change Mechanisms of Heat Flow Conduction Convection Radiation
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Review - Heat and Temperature Change
Adding heat to object causes temperature change. π=ππβπ Q β Quantity of Heat (J) (cal) m β Mass (kg) c β Specific Heat ( J/kg CΒ°) ΞT β Temperature change (CΒ°)
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Temperature and phase change
Block of ice at -40Β°C Heat as ice to 0Β°C Melt at 0Β°C Heat as water to 100Β°C Vaporize at 100Β°C Heat as vapor to ??Β° C
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Specific and Latent Heat
Specific Heat involves temperature change π=ππβπ Latent Heat involves phase change π=ππΏ Latent Heat problems involve: No change in temperature Ice - > liquid, liquid -> gas Depends only on mass and Latent Heat
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Heat and Phase Change Latent heats are enormous, compared to specific heats! (Be careful with extra 0βs and k-prefixes!)
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Example 14-7 Step 1 β cool water from 20 C to 0C
π 1 =ππβπ= 1.5 ππ π½ ππ πΆ 20 πΆ = ππ½ Step 2 β freeze all water at 0 C π 2 =ππΏ= 1.5 ππ 333,000 π½ ππ (no temperature here) =499.5 ππ½ (careful with 0βs and k-prefixes!) Step 3 β cool frozen water from 0 C to -12 C π 3 =ππβπ= 1.5 ππ π½ ππ πΆ 12 πΆ (now ice) =37.8 πΎπ½ Total for whole process π= π 1 + π 2 + π 3 =125.6 ππ½ ππ½+37.8 ππ½=662.9 ππ½
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Example 14-8 β Does ice melt? (1)
Requirements Heat lost by water = heat gained by ice Final temperature same Final phase same (except at melting or boiling point) Possible outcomes All ice melts, πβ₯0 πΆ Some ice melts, π=0 πΆ Some water freezes, π=0 πΆ All water freezes, πβ€0 πΆ Must βexperimentβ a little, to see which it isβ¦β¦
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Example 14-8 β Does ice melt? (2)
Since 0 C is where everything gets complicated, find the heats required to bring everything to 0 C Cool all water down to 0 C π 1 =ππβπ= 3 ππ π½ ππ πΆ 20 πΆ = ππ½ Warm all ice up to 0 C π 2 =ππβπ= 0.5 ππ π½ ππ πΆ 10 πΆ =10.5 ππ½ Melt all ice at 0 C π 3 =ππΏ= 0.5 ππ 333,000 π½/ππ =166.5 ππ½ Conclusion: The ice doesnβt have a snowballβs chance! To coexist with the water as ice, it has to bring the water down to at least 0Β°C. To do that it has to absorb kJ, which is more than enough to warm it to 0Β°C and melt it all.
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Example 14-8 β Does ice melt? (3)
Now you know final temperature must be > 0Β°C To balance the heat: Bring all the ice up to 0Β°C (10.5 ππ½) Melt all the ice at 0Β°C (166.5 ππ½) Bring all the melted ice up above 0Β°C (???) Bring the tea down not quite to 0Β°C ( ππ½ β ???) This will simultaneously satisfy: Heat lost by water= heat gained by ice Final temperature same Final phase same (except at melting or boiling point)
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Example 14-8 β Does ice melt? (4)
Solution π»πππ‘ πππ π‘ ππ¦ π‘ππ πππππππ π‘π π π >0 = π»πππ‘ ππππππ ππ¦ πππ π€ππππππ π‘π 0 πΆ + π»πππ‘ ππππππ ππ¦ πππ ππππ‘πππ ππ‘ 0πΆ + π»πππ‘ ππππππ ππ¦ ππππ‘ππ πππ π€ππππππ π‘π π π >0 Plug in numbers 3 ππ π½ ππ πΆ 20 πΆβ π π =10.5 ππ½ ππ½ ππ π½ ππ πΆ π π β0 πΆ ππ½β( π½ πΆ) π π =10.5 ππ½ ππ½+( π½ πΆ) π π ( π½ πΆ) π π =74.16 π½ π» π =π.πΒ°πͺ
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Example 14-8 β Does ice melt? (modified 1)
Double amount of ice to 1 kg Cool all water to 0 C (same) π 1 =ππβπ= 3 ππ π½ ππ πΆ 20 πΆ = ππ½ Warm all ice to 0 C (double) π 2 =ππβπ= 1 ππ π½ ππ πΆ 10 πΆ =21 ππ½ Melt all ice at 0 C (double) π 3 =ππΏ= 1 ππ 333,000 π½/ππ =333 ππ½ Conclusion: The ice definitely comes up to 0Β° C, as thatβs the first place the kJ from the water will go. But it doesnβt all melt, as that would consume more energy than comes out of the water!
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Example 14-8 β Does ice melt? (modified 2)
Now you know final temperature must be = 0Β°C To balance the heat: Bring all ice up to 0Β°C (21 ππ½) Melt some ice at 0Β°C (??) Bring all tea down to 0Β°C ( ππ½) This will simultaneously satisfy: Heat lost by water= heat gained by ice Final temperature same Final phase same (except at melting or boiling point )
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Example 14-8 β Does ice melt? (modified 3)
Solution π»πππ‘ πππ π‘ ππ¦ π‘ππ πππππππ π‘π 0πΆ = π»πππ‘ ππππππ ππ¦ πππ π€ππππππ π‘π 0 πΆ + π»πππ‘ ππππππ ππ¦ ππππ‘πππ ππππ‘ ππ πππ ππ‘ 0πΆ Plug in numbers ππ½=π 333 ππ½ ππ +21 ππ½ π=0.69 ππ With 1 kg of ice, only 0.69 kg of it melts PS: Another example - McDonaldβs coffee with βΒ½ inch iceβ trick
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Example 14-9 β Latent heat of mercury
No βexperimentingβ required β you know final temperature and phase. Solution π»πππ‘ πππ π‘ ππ¦ π€ππ‘ππ πππππππ π‘π πΆ+βπππ‘ πππ π‘ ππ¦ π΄π ππ’π πππππππ π‘π 16.5 πΆ = π»πππ‘ ππππππ ππ¦ πππππ’ππ¦ ππ ππππ‘πππ ππ‘ β39πΆ + π»πππ‘ ππππππ ππ¦ ππππ‘ππ πππππ’ππ¦ π€ππππππ π‘π 16.5 πΆ π π€ππ‘ππ π π€ππ‘ππ β π π€ππ‘ππ + π ππ’π π ππ’π β π ππ’π = π π»π πΏ π»π +π π»π π π»π β π π»π 1.2 ππ π½ ππ πΆ 3.5 πΆ ππ π½ ππ πΆ πΆ = 1 ππ πΏ π»π + 1 ππ π½ ππ πΆ πΆ 17.58 ππ½+1.57 ππ½= 1 ππ πΏ π»π ππ½ πΏ π»π = ππ½ ππ
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Problem β 24 - Ice in liquid nitrogen
Donβt need to βexperimentβ since you know final temperature/phase! Nitrogen already at its boiling point, just need to vaporize. Heat lost by ice = latent heat gained by nitrogen π πππ π πππ β π πππ = π πππ‘ππππππ‘ πΏ πππ‘πππππ Filling in, using ΞC = ΞK and 2100 J = 2.1 kJ 0.03 ππ ππ½ ππ πΎ πΎβ77 πΎ = π πππ‘πππππ (200 ππ½/π) ππ½= π πππ‘πππππ (200 ππ½/π) π πππ‘ππππ =0.062 ππ= 62 π
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Problem β 25 β Ice in Water Donβt need to βexperimentβ since you know final temperature/phase! Heat lost by water + heat lost by cup = heat gained by ice (-8.5 -> 0) + heat gained by melting ice ( 0 ) + heat gained by melted ice (0 -> 17) π π€ππ‘ππ π π€ππ‘ππ β π π€ππ‘ππ + π ππ’π π ππ’π β π ππ’π =π πππ π πππ β π πππ + π πππ πΏ πππ + π ππππ‘ππ.πππ π ππππ‘ππ.πππ β π ππππ‘ππ.πππ 0.31 ππ π½ ππ πΆ 3 πΆ ππ π½ ππ πΆ 3 πΆ = π πππ π½ ππ πΆ 8.5 πΆ + π πππ 333,000 π½ ππ + π πππ π½ ππ πΆ 17 πΆ 3893 π½ π½= π πππ 17,850 π½ ππ +333,000 π½ ππ +71,162 π½ ππ π πππ = ,012= ππ=9.8 π
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Problem β 26 β Water in Iron boiler
πππ€ππβπ‘πππ=π»πππ‘ ππ To reach boiling point: (52,000 ππ½ β) π‘πππ = 830 ππ ππ½ ππ πΆ 82 πΆ ππ ππ½ ππ πΆ 82 πΆ (52,000 ππ½ β) π‘πππ = 284,899 ππ½+8,487 ππ½ π‘πππ=5.64 βππ’ππ To turn all to steam: (52,000 ππ½ β) π‘πππ = 830 ππ ππ½ ππ (52,000 ππ½ β) π‘πππ = 1,875,800 ππ½ π‘πππ=36. 07βππ’ππ
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Problem β 28 β Steam and Ice
Donβt need to βexperimentβ since you know final temperature/phase Heat lost condensing steam (100) + heat lost cooling condensed steam (100 -> 20) = heat gained by melting ice ( 0 ) + heat gained by heating melted ice (0 -> 20) π π π‘πππ πΏ π π‘πππ +π πππππππ ππβπ π‘πππ π π€ππ‘ππ β π πππππππ ππβπ π‘πππ = π πππ πΏ πππ + π ππππ‘ππβπππ π π€ππ‘ππ β π ππππ‘ππβπππ π π π‘πππ (2260 ππ½ ππ) + π π π‘πππ ( ππ½ ππ πΆ)(80 πΆ) =(1 ππ)(333 ππ½ ππ)+(1 ππ) ( ππ½ ππ πΆ)(20 πΆ) π π π‘πππ ( ) ππ½ ππ= ππ½ π π π‘πππ = =0.16 ππ=160 π
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Problem β 29 β Mercury heat of fusion
Donβt need to βexperimentβ since you know final temperature/phase Heat lost by water + heat lost by calorimeter = + heat gained by melting Hg (-39 ) + heat gained by melted Hg (-39 -> 5.06) π π€ππ‘ππ π π€ππ‘ππ β π π€ππ‘ππ + π πππ π πππ β π πππ = π π»π πΏ π»π + π π»π π ππππ‘ππβπ»π β π ππππ‘ππβπ»π 0.4 ππ π½ ππ πΆ πΆ ππ π½ ππ πΆ πΆ =(1 ππ) πΏ π»π +(1 ππ)(138 π½ ππ πΆ)(44.06 πΆ) 12,960 π½+4,319 π½= 1 ππ πΏ π»π +6,080 π½ πΏ π»π =11,199 π½ ππ
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Problem β 30 β Bullet penetrating ice
Kinetic energy = heat of melting 1 2 π ππ’ππππ‘ π£ 2 = π ππππ‘ππ πΏ 1 2 (0.07 ππ π π 2 = π ππππ‘ππ 333,000 π½ ππ π½= π ππππ‘ππ 333,000 π½ ππ π ππππ‘ππ = ππ=6.6 π
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