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CHEMICAL REACTIONS
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KINETIC MOLECULAR THEORY
Matter is composed of tiny particles called atoms or molecules These particles are always undergoing constant, random (Brownian) movement.
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Collision Theory Reactants must collide with the correct orientation and with sufficient energy.
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Orientation – position in space
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Effect of Collision Energy on Chemical Reactions
SUFFICIENT ENERGY = NEW PRODUCTS INSUFFICIENT ENERGY = NO NEW PRODUCT
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Reactions must have a minimum activation energy…if too little, no reaction.
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A reaction takes place if the energy available is greater than the minimum activation energy.
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Exothermic (Exogonic) Reaction = Energy of the Reactants > Energy of the Products
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Endogonic (Endothermic) Reactions – Energy of the Reactants < Energy of the Products
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STEPS IN CHEMICAL REACTIONS
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1. Bond Breaking
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2. Formation of Activated Complex – an intermediate product
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3. Formation of Product
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FACTORS AFFECTING REACTION RATES
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1. Nature of Reactants A reaction could only take place if the reactants are reactive enough to form a new product. Ex. Neon gases are inert and will not react with oxygen while sodium metal will burn if exposed to O2 gas.
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2. Temperature
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3. Concentration of Reactants
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Presence of catalyst or inhibitor
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Effect of the presence of catalyst on a reaction
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END OF TOPIC
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Le Chatelier's Principle
If a system at equilibrium is altered in a way that disrupts the equilibrium, the system will shift in such a way as to counter the change.
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Rates of Reaction for Reversible Reactions
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Changes in Concentrations for a Reversible Reaction
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Effect of Increased Concentration on Equilibrium
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Change in Rates When Reactant Added
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Effect of Decreased Concentration on Equilibrium
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Change in Rates When Product Removed
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