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Write the charges next to the different ions, use the examples given to help you
Positive ions Charge Negative ions ammonium NH4+ 1+ chloride Cl− 1− potassium K+ bromide Br− sodium Na+ iodide I− calcium Ca2+ 2+ hydroxide OH− magnesium Mg2+ nitrate NO3− copper(II) Cu2+ oxide O2− 2− iron(III) Fe3+ 3+ carbonate CO32− aluminium Al3+ sulfate SO42−
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Answers
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Ionic compounds Saturday, 24 November 2018
Key question: How are the formulae of ionic compounds worked out? Key words: Ionic compounds Formula Compound ions Starter: How is the periodic table useful when finding out the formula of different ions. Specs:
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Salt An ionic compound composed of positive ions (cations) and negative ions (anions).
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Working out a formula Ionic compounds contain ions. You can work out the formula of an ionic compound if you know which atoms are in it. Ionic compounds are electrically neutral ( no charge) because they contain equal numbers of positive and negative charges. In NaCl one Na+ is needed for every Cl-. So 1+ and 1- ion balance each other out. The overall charge is 0.
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Working out a formula Many ionic compounds have ions with different numbers of charges. For example calcium chloride. Give the group number for Ca and Cl: Ca group 2, Cl is in group 7. How many electron would Ca lose? 2 How many electron can 1 Cl gain? 1 How many Cl is needed for 1 Ca? 2, Ca wants to lose 2e-, hence 2 Cl will be needed What are the charges on the ions? Cl – and Ca2+ What is the overall charge on the ionic compound? 0 (2 Cl have -- and Ca has 2+, this will balance the charges out)
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Working out a formula At this point we know there are two chloride ions bonding with one calcium ions. A formula has to contain symbols of participating ions and the number of these ions. Metals should come first then non-metal. CaCl What about the numbers? There is 1x Ca, but 2xCl. In chemistry we do not really write 1 (soooo lazy), but other numbers must be indicated by a subscript (small number on the bottom) Ca1Cl2 → CaCl2.
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Working out a formula In an ionic compound ions have charges but the overall charge of the compound must be 0.
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Compound Ions Compound ions contain more than one element. For example the nitrate ion NO3- contain one nitrogen joined to 3 oxygen atoms and an extra electron. O N O O
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Common Compound Ions You need to learn these!!!
Name Symbol Charge Hydroxide OH- 1- Nitrate NO3- Carbonate CO32- 2- Sulphate SO42- Ammonium NH4+ 1+
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Writing these in a formula
If two or more compound ions of the same type are needed in a formula, the ion must be written inside brackets. For example: Magnesium Nitrate is Mg(NO3)2 This shows that the two positive charges on Mg2+ are balanced by the two negative charges from two NO3- ions.
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To help use your starter question
Negative ions chloride iodide oxide Positive ions potassium calcium iron(III) aluminium Negative ions hydroxide nitrate carbonate sulfate Positive ions sodium magnesium copper(II) aluminium ammonium
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cation + anion -> Ionic Compound
What’s in the name? cation + anion -> Ionic Compound Ionic compounds ending in ‘-ide’- e.g Sodium Chloride ‘-ide’ ending compounds occur when two different elements combine. Ionic compounds ending in ‘-ate’- e.g Copper sulphate ‘-ate’ ending compounds occur when three or more different elements combine and one of them is oxygen. e.g. (Copper Sulphate= copper +sulphur + oxygen) The ending gives a clue that the chemical is a compound. 4
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Correctly name the following ionic compounds:
a NaI b CaCl2 c KOH e Al2O3 g Mg(NO3)2 h CaCO3 i Na2SO4 B-grade a sodium iodide b calcium chloride c potassium hydroxide e aluminium oxide g magnesium nitrate h calcium carbonate i sodium sulfate
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