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Quantum Mechanical View of Atoms

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Presentation on theme: "Quantum Mechanical View of Atoms"— Presentation transcript:

1 Quantum Mechanical View of Atoms

2 The electron can be thought of as spread out in space as a “cloud”.

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4 Quantum Mechanics of the Hydrogen Atom

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6 n – principal quantum number, positive integer;
l – orbital quantum number, is related to the magnitude of the angular momentum of the electron; at given n can take integer values from 0 to (n-1); ml – magnetic quantum number, is related to the direction of the electron’s angular momentum, and it can take an integer values from –l to +l.

7 Zeeman Effect

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9 Spin Quantum Number, ms

10 Conceptual Example: Possible States for n=3
How many different states are possible for an electron whose principal quantum number is n=3?

11 Selection Rule Another prediction of quantum mechanics is that when a photon is emitted or absorbed, transitions can occur only between states with values of l that differ by one unit.

12 The Exclusion Principle

13 No two electrons in an atom can occupy the same quantum state.

14 Complex Atoms and Periodic Table of Elements

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16 Conceptual Example Which of the following electron configurations are possible, and which forbidden ?


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