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Quantum Mechanical View of Atoms
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The electron can be thought of as spread out in space as a “cloud”.
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Quantum Mechanics of the Hydrogen Atom
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n – principal quantum number, positive integer;
l – orbital quantum number, is related to the magnitude of the angular momentum of the electron; at given n can take integer values from 0 to (n-1); ml – magnetic quantum number, is related to the direction of the electron’s angular momentum, and it can take an integer values from –l to +l.
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Zeeman Effect
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Spin Quantum Number, ms
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Conceptual Example: Possible States for n=3
How many different states are possible for an electron whose principal quantum number is n=3?
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Selection Rule Another prediction of quantum mechanics is that when a photon is emitted or absorbed, transitions can occur only between states with values of l that differ by one unit.
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The Exclusion Principle
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No two electrons in an atom can occupy the same quantum state.
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Complex Atoms and Periodic Table of Elements
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Conceptual Example Which of the following electron configurations are possible, and which forbidden ?
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