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Chemistry 11 Challenge Question
A mixture of Cu2O and CuO of mass g is reduced to copper metal with hydrogen. If the mass of pure copper isolated was g, determine the percent (by mass) of CuO in the original sample. Let Ω equal the mass of Cu2O (8.828 – Ω) g Cu2O Ω g CuO Ω g Cu2O x 1mol x 2 mol Cu x g = Ω g Cu 143.0 g 1 mol Cu2O 1 mole (8.828 – Ω) g CuO x 1mol x 1 mol Cu x g = Ω g Cu 79.5 g 1 mol CuO 1 mole Ω g Ω g = total grams Cu Ω = total grams Cu
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Grams Cu = Grams Cu Ω = Ω = Ω = mass Cu2O = g – Ω = mass CuO = g Do not round until the end! % CuO = g x 100 % = % 8.828 g 3 sig figs due to the molar masses!
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A container of nickel II sulphate has been accidentally contaminated with
nickel III sulphate. The total mass of both sulphates was g. Through a single replacement reaction with Zn, the nickel was extracted from both sulphates and was found to have a mass of g. What was the original masses of the nickel II sulphate and nickel III sulphate before they were mixed? Let Ω equal the mass of NiSO4 NiSO4 Ω g Ni2(SO4)3 (24.44 – Ω) g Ω g NiSO4 x 1mol x 1 mol Ni x g = Ω g Ni 154.8 g 1 mol NiSO4 1 mole (24.44 – Ω) g Ni2(SO4)3 x 1mol x 2 mol Ni x g = Ω g Ni 405.7 g 1 mol Ni2(SO4)3 1 mole Ω g Ω g = total grams Ni Ω = total grams Ni
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2 4 . 4 4 - 9. 7 7 1 4 . 6 7 Round to 2nd decimal Grams Ni = Grams Ni
Ω = A = Ω = mass NiSO4 = 9.77 g – Ω = mass Ni2(SO4)3 = g Round to 2nd decimal A has 3 sig figs - molar masses! Ni2(SO4)3 has 4 sig figs!
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