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Published byLetitia Richard Modified over 6 years ago
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and the table of specific heats. and the table of phase changes
THINGS TO REMEMBER ΔH for temperature changes uses the formula ΔQ = c m ΔT and the table of specific heats. ΔH for phase changes uses the formula ΔQ = m l and the table of phase changes
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STUDY OF THE EFFECTS OF WORK, HEAT AND ENERGY ON A SYSTEM
THERMODYNAMICS STUDY OF THE EFFECTS OF WORK, HEAT AND ENERGY ON A SYSTEM
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ZEROTH LAW – Law of Thermodynamic Equilibrium
Heat energy moves from hot to cold objects until a state of thermodynamic equilibrium (same temperature = same KE) exists between the objects
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FIRST LAW – Law of Conservation of Heat Energy
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SECOND LAW – Law of Entropy
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THIRD LAW – Absolute Zero
As the absolute temperature approaches zero (0 K), the entropy of the system approaches zero.
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Example: An 8.0 g ice cube at -10oC was placed in a Thermos flask containing 100 ml of water at 20oC. The specific heat of ice is 2.05 J/g-K, the specific heat of water is J/g-K and the heat of fusion of ice-water is 334 kJ/g-K. What is the final equilibrium temperature?
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= 164 J + 2672 J + 33.49 J/oC Tf + 418.6 J/oC Tf – 8372 J
ΔQ = Hgained + Hlost = 0 = cicemice(0 – (-10)oC) + mice (Hf) + cwmice(Tf-0oC ) + cwmw(Tf-20oC) = (2.05 J/g-oC)(8.0 g)(10oC) + (8.0 g)(334 J/g-oC) J/g-oC)(8.0 g) (Tf) + (4.186 J/g-oC)(100 g)(Tf-20oC) = 164 J J J/oC Tf J/oC Tf – 8372 J = J J/oC Tf Tf = J/(-452 J/oC) = 12.2 oC
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