1. ORGANIC CHEMISTRY CHAPTER-1
Nomenclature of organic compounds & Functional groups identification By
Dr. Ghulam Abbas

2. Nomenclature
It is important that organic compounds are corrrectly named so that there can be absolutely no confusion about what compounds are actually being reported or described. The International Union of Pure and Applied Chemistry (I.U.P.A.C.) which was formed in 1919, reviews to standardise nomenclature. The following guidelines for organic nomenclature are based on the definitive rules published by I.U.P.A.C.1 (the International Union of Pure and Applied Chemistry).
I.U.P.A.C. Nomenclature for Organic Chemistry, Sections A, B and C (combined edition), Butterworths Scientific Publications, London, 1971.

3. HYDROCARBONS
(i) The Alkanes (CnH2n+2)

4. Rules for Naming Organic Compounds
The following steps are taken in naming an alkane with a branched chain:
Select the longest continuous carbon chain and select the appropriate alkane name.
2) Number the longest chain so that substituents have the lowest possible numbers.
3) Name all of the side chains (carbon chains attached to the longest chain) and list them in alphabetical order.
4) use multiplicative prefixes such as “di-“ (2), “tri-“(3), "tetra-" (4) etc. if two, three or four similar substititents are attached. and insert location numbers before each of the side chain names.

5. Methyl Ethyl pentane Methyl Pentane Methyl Hexane Hexane C 1. C 2. H C
This is longest continuous chain
Methyl Hexane
Hexane H C 3.
Ethyl pentane

7. Shorthand notation? C H C H
Name?
3-ethyl-2,4 dimethyl hexane

8. The Alkenes (CnH2n)
ene=One double bond, diene =two double bonds
(a) Select and name the longest carbon chain containing the double bond.
(b) Change the “ane" of the alkane name to “ene".
(c) Number the carbon chain giving the double bond the lowest possible location number.
(d) Name side chains in the usual way.

9. The Alkynes (CnH2n-2)
These are named in identical fashion to alkenes except that "ene" in the alkene name is replaced by: "yne" 1 triple bond, "diyne" 2 triple bonds
"triyne" 3 triple bonds etc.

10. COMPOUNDS CONTAINING HALOGENS AND NITRO GROUPS
The halogens (F, Cl, Br, I) and the nitro group (-NO2) are always named as prefixes in the same way as side chains on hydrocarbons. The prefixes are as follows:

11. Alcohols
-OH as the principle functional group, here “ane” is converted into “ol”

12. Aldehydes
Aldehydes formally derived from acids having a trivial name are named by adding "-aldehyde" to the trivial stem (see Section 3), otherwise the suffix “-al” is used.

13. Ketones
Ketones are named by adding the suffix "-one" to the stem of the parent carbon chain.

14. Carboxylic acids are named by identifying the longest carbon chain containing the carboxylic acid functional group and using this carbon chain as the stem for the carboxylic acid name. The ending "-oic acid" is added to the stem to indicate that the compound is a carboxylic acid.

15. Naming Esters Esters give flowers and fruits their pleasant fragances and flavors.
Name the alkyl from the alcohol –O-
Name the acid with the C=O with –ate O
 methyl
CH3 — C—O —CH3
Ethanoate methyl ethanoate (IUPAC)
(acetate) methyl acetate (common)

16. Some Esters and Their Names
Flavor/Odor
Raspberries
HCOOCH2CH3 ethyl methanoate (IUPAC)
ethyl formate (common)
Pineapples
CH3CH2CH2 COOCH2CH3
ethyl butanoate (IUPAC)
ethyl butyrate (common)

17. propyl acetate (common)
Q. Give the IUPAC and common names of the following compound, which is responsible for the flavor and odor of pears. O 
CH3 — C—O —CH2CH2CH3
Answer:
 propyl
propyl ethanoate (IUPAC)
propyl acetate (common)

18. Q. Draw the structure of the following compounds:
3-bromobutanoic acid
Ethyl propionoate
Answer:
A. 3-bromobutanoic acid Br |
CH3CHCH2COOH
B. Ethyl propionoate O 
CH3 CH2 COCH2CH3 OR
CH3CH2COOCH2CH3

20. Ethers
In the naming of ethers as alkyloxy derivatives of alkanes, it is general practice to shorten
the names of compounds containing four or less carbons to alkoxy derivatives (i.e., omit the
syllable "-yl-°'), e.g., methyloxy becomes methoxy, ethyloxy becomes ethoxy, but pentyloxy

21. Amine: The systematic method of naming amines, whereby "-amine" is added to the principal chain name is, in practice, only rarely used and an older method is in common (I.U.P.A.C. accepted) use.

22. THE END