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CHEM 433 – 10/11/11 III. 1st Law: “Machinery” ( )

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Presentation on theme: "CHEM 433 – 10/11/11 III. 1st Law: “Machinery” ( )"— Presentation transcript:

1 CHEM 433 – 10/11/11 III. 1st Law: “Machinery” (2.10-2.12)
- Properties of the Enthalpy (dH=?) - Isothermal Compressibility - The Joule Thompson Effect READ: FINISH CHAPTER 2 HW # 4 DUE Friday HW #3 (formerly #4) AVE = 23/30 (76%)

2 What is T for an ideal gas ?
How much does the volume change when 50 cm3 of H2O is subjected to 1000 atm of additional pressure? T (H2O) = 4.95 x 10-5 atm-1.

3 Trust me - or Atkins: U + pV is equal on both sides and thus constant.

4 James Prescott Joule William Thompson - aka “Lord Kelvin”

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7 For CO2  = K/atm. By how much does the Temp change when CO2 expands (w/ constant enthalpy) across a 1 atm pressure difference?

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