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Acids, Bases, & pH Section 2.6
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Learning Objectives Contrast acids and bases & discuss their properties. Convert the hydrogen ion concentration of a solution to a pH value. Describe how buffers help minimize changes in pH.
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Pure Water is Neutral Water dissociates into hydrogen ions (H+) and hydroxide ions (OH-) One water molecule breaks down into one of each ion H+ and OH- are equal in concentration Since H+ and OH- are equal in concentration pure water is neutral pH = 7
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Acids & Bases Acid = a solution that has more hydrogen ions (H+) than hydroxide ions (OH-) pH < 7 Donates H+ ions Base = a solution that has more hydroxide ions (OH-) than hydrogen ions (H+) pH > 7 Accepts H+ ions
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(Higher concentration of H+) (Lower concentration of H+)
pH scale The pH Scale Each pH unit represents a tenfold change in concentration of H+ Logarithmic scale H+ OH– Lemon juice; gastric juice (Higher concentration of H+) Increasingly ACIDIC Grapefruit juice Acidic solution Tomato juice Urine NEUTRAL [H+] = [OH–] PURE WATER Human blood Seawater Neutral solution (Lower concentration of H+) Increasingly BASIC Milk of magnesia Household ammonia Household bleach Oven cleaner Basic solution Figure 2.15
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pH Indicators Boiled cabbage creates a bluish juice that can be used to test pH of substances Turns blue in bases Turns red in acids
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pH Indicators Other indicators: pH paper Blue litmus paper
Turns red in acids Red litmus paper Turns blue in bases phenolphthalein turns pink in presence of bases
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Calculating Ion Concentrations
[H+] [OH-] = 1 x 10-14 Ex. If [H+] = 0.001, then what is the [OH-]? Answer: [OH-] = 1 x 10-11 pH 7 is 1 x 10-7 Practice Problem: What pH is a solution that has a [H+] of 1 x ? Answer: pH 10
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Buffers Buffer = substance that resists pH change
Accepts H+ ions when they are in excess and donates H+ ions when they are depleted Cells need a stable pH in order to function properly Most cells have a pH close to 7
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