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Bell Ringer (on quarter sheet!)
Please have the following out on your desk: Where are the following?? Alkaline Earth metal - Labeled Periodic Table from yesterday Element with 3 valence e- - WS from yesterday (electron configuration) Element that needs 2 e- Total of 8 valence e- -Periodic Table Will form a +1 ion Halogens When completed, turn in to the box
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New Terminology Berkner The Atom Energy Levels Sublevels Orbitals
Electrons Hallways Classrooms on each hall Desks You
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S orbitals hold 2 e- P orbitals hold 6 e- D orbitals hold 10 e-
Dumb bell Spherical D orbitals hold 10 e- F orbitals hold 14 e- Eliptical
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We will learn three ways to show electron configuration
Electron Configuration Notation Orbital Notation Lewis Dot Notation (1st 3 periods)
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1. Electron Configuration
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Look at the electron configuration for Chromium:
1s2 2s2 2p6 3s2 3p6 4s2 3d4 Highlight the energy levels in yellow Underline the sublevels in red Circle the electrons in green
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Look at the electron configuration for Chromium:
1s2 2s2 2p6 3s2 3p6 4s2 3d4 What does 3d4 mean? 4 electrons in d shaped orbital 3 energy levels away from the nucleus How many valence electrons does chromium have? 2 electrons in outermost energy levels (4th energy level)
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Electron Configuration Notation
Write coefficient for energy level. Write letter for sublevel Superscript (number on top) shows # of electrons at that level. Na 1s22s22p63s1 C 1s22s22p2 It can also be expressed like this. Nobel Gas Notation [Ne] 3s1 [He] 2s2 2p2
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The Order Electrons Fill Orbitals
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Electron Configuration of Zr
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d2
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Practice Write the long hand configuration for the following elements.
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Shorthand Notation
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How do I write less? Na was 1s22s22p63s1
In shorthand, find the previous noble gas (one row up) Neon, put it in brackets, then continue with the next orbital (period#,s) [Ne] replaces the 1s22s22p6 [Ne]3s1 C was 1s22s22p2 shortcut is [He]2s22p2
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Core Notation of Sn Locate Sn on the periodic table
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Shorthand Electron Configuration of Sn
Sn [Kr] The noble gas core is Kr
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Sn [Kr]5s2 The noble gas core is Kr
From Kr, go 2 spaces across the s-block in the 5th row 5s2
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Sn [Kr]5s24d105p2 The noble gas core is Kr
From Kr, go 2 spaces across the s-block in the 5th row 5s2 Then go 10 spaces across the d-block on the 5th row 4d10 Finally go 2 spaces into the p-block on the 5th row 5p2
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2. Orbital Notation Tells in more detail where the electrons are:
1. What energy level they are on 2. What sublevel they are on 3. What axis they are on (x,y,z) 4. What spin they have (clockwise/counterclockwise)
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Aufbau Principle Each electron occupies the lowest energy orbital available. The “orbital diagram” is… Page 135
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The “d” orbitals fill up in levels 1 less than the period number, so the first d is 3d even though it’s in row 4. S1 S2 1 2 3 4 5 6 7 p1 p2 p3 p4 p5 p6 3d 4d 5d
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Aufbau Diagram – if you want to use this, memorize how to draw it
S levels hold 2 e- P levels hold 6 e- D levels hold 10 e- F levels hold 14 e- Look at the periodic table, and the blocks, how can you easily remember these numbers?
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Hund’s Rule If you have more than one orbital in a sublevel (p,d,f), place one electron in each orbital before you double up.
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Pauli Exclusion Principle
Electrons have opposite spin directions Maximum of two electrons may occupy a single atomic orbital
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Orbital Notation Na ___ ___ ___ ___ ___ ___ 1s 2s 2p 2p 2p 3s
Letters/numbers represent energy level (remember start at bottom of chart) ___ lines represent 1 orbital each.
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Practice Show orbital notation for Cl and As Cl As
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Practice Orbital Diagram!
Refer to a periodic table and write the electron configurations of these atoms. Write the orbital diagram for the orbitals not in the noble gas core. Zn I
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Lewis Dot Structures
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Lewis Dot Notation Lewis Dot diagrams show electrons available for bonding (the outermost electrons, valence) Valence electrons = the total electrons in the last principal quantum level (highest coefficient)
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Reminders Electron Configuration WS (picked up yesterday) will be due on Friday, 9/26 Skills check on electron configuration on Friday, 9/26 e- configuration Battleship tomorrow!
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Exit Ticket Write the electron configuration for Oxygen
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