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The Ideal Gas Law Chapter 11 Section 3
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Standard Molar Volume of a Gas
Assume the gas is an ideal gas. Standard molar volume of a gas: the volume occupied by one mole of a gas at STP, the value is 22.4 L Therfore, if you know the volume of gas at STP, you can find the number of moles by using conversion factor mole 22.4 L
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Continued Knowing the mol of the gas at STP, you can find the volume of the gas L 1 mole At STP, what is the volume of 7.08 mol of nitrogen gas?
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Another Problem A sample of hydrogen gas occupies L at STP. How many moles of the gas are present?
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PV = nRT The Ideal Gas Law
Ideal gas law: the mathematical relationship among pressure, volume, temperature, and the number of moles of a gas behaving ideally. PV = nRT “R” is a constant (.0821 L*atm/mol*K) “n” is the number of moles of gas in sample
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The Ideal Gas Constant The constant “R” is the ideal gas constant
The value and units of “R” vary according to the units used for P and V If P is in kPa, and V is in L, then R = 8.314 Temperature has to be K
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Problem A tank of hydrogen gas has a volume of L and holds 14.0 mol of the gas at 12°C. What is the pressure of the gas in kPa?
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Another Relationship You can use the ideal gas law to find the molar mass of a substance. Remember that molar mass = grams/mole. M = molar mass m = mass of the substance R, T, P, and V stand for the same quantities.
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Problem What is the molar mass of a gas which has a mass of g and a volume of 8.13 L at 20.0 °C and 99.2 kPa?
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Problems Calculate the volume that a mol sample of a gas will occupy at 265 K and a pressure of 91.2 kPa. What is the pressure in kPa of a mol sample of helium gas at a temperature of 20.0°C if its volume is L?
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Another Problem Determine the kelvin temperature required for mol of gas to fill a balloon to 1.20 L under kPa
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