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Exothermic or Endothermic?
Exothermic releases energy into the surrounding as heat. As a result, the temperature of the surrounding increases. Endothermic absorbs energy from the surrounding. As a result, the temperature of the surrounding decreases.
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Endothermic or Exothermic?
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5.2 Calorimetry and Enthalpy
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Task Read pages In your notebook, write the definitions of the keywords
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Specific Heat Capacity
Substance A has a specific heat capacity of 4.18 and substance B has specific heat capacity of What does this mean? This means that A needs more thermal energy than B to raise the temperature of A by 1 degrees.
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Calorimetry Calculations
q = mcΔT q= total amount of thermal energy absorbed or released m=mass of the substance c=specific heat capacity ΔT = change in temperature (final-initial)
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Sample Problem 1 Let’s do sample problem 1 from page 295 together!
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You have to finish it in class!
Task Do questions 1-8 from the handout. You have to finish it in class!
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Enthalpy Change Enthalpy (H) the total amount of thermal energy in a substance Enthalpy Change (ΔH) the energy released to or absorbed from the surroundings during a chemical or physical change Molar Enthalpy Change (Δ 𝐻 𝑟 ) the enthalpy change associated with a physical, chemical, or nuclear change involving 1 mol of a substance.
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Calculating ΔH It is hard to find the enthalpy (H) of a given substance but we can calculate enthalpy change (ΔH) of a reaction What is ΔH? ΔH = 𝐻 𝑝𝑟𝑜𝑑𝑢𝑐𝑡𝑠 − 𝐻 𝑟𝑒𝑎𝑐𝑡𝑎𝑛𝑡𝑠 If ΔH > 0, endothermic reaction (positive) If ΔH < 0, exothermic reaction (negative) Also, as long as pressure stays constant, ΔH = |q| We know how to calculate q (q = mcΔT) So, if we know q for a reaction, we know the value of ΔH
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Molar Enthalpy Change (Δ 𝐻 𝑟 ) is the general formula for molar enthalpy change for any reaction type. There are different types of molar enthalpy changes (Table 2 on page 299):
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Connecting Enthalpy Change and Molar Enthalpy Change
The amount of enthalpy change depends on the quantity of matter that undergoes the change For example, it takes more energy to convert 1 L of liquid water to water vapor than it does for 500 mL So, to calculate the enthalpy change for some amount of substance other than 1 mol, you need to use the following formula: ΔH = nΔ 𝐻 𝑟
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Task Copy down Sample Problem 1 and 2 from the board
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HOMEWORK Required Reading: p. 292-306
Make notes on Representing Molar Enthalpy Changes and copy down the sample problems Do practice problems 1-4 from page 301 Do questions 1-7 on page 306
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