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Classification of Stony Meteorites
EL (0.8%) opx, no oliv Enstatite % Feo (1.6%) EH (0.8%) opx, no oliv - 25% Feo H (30%) % Feo Ordinary (78%) L (40%) % Feo Chondrites (85-87%) LL (7%) % Feo - chondrules - oliv, opx, Feo CV (1%) volatile depleted refractory lithophile enriched - refractory inclusions CO (1%) volatile depleted STONES Carbonaceous matrix < 30% < 30% Feo (4.8%) CM (2%) slight volatile depletion (94-97%) matrix > 30% CI (0.8%) volatile-rich - hydrated silicates - no oliv or chondrules Aubrites enstatite & Fe alloy Ureilites shock-melted carbonaceous chondrites? (0.4%) olivine + Fe alloy, diamonds Achondrites Lunar feldspar breccia (10-12%) SNC basaltic to ultramafic composition (1%) shocked, young (1.4 bys) - Martian rare-gas isotopic ratios Eucrites basaltic composition (2.8%) largely of opx & felds - assoc: diogenites (opx) & howardites (breccias) - old (4.5 bys)
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Allende
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Chondrite 32% Feo core + 68% mantle
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15 – 20 % melting MgO = 37.8 Al2O3 = SiO2 = CaO = FeO = Total = 98.8
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Primitive mantle: MgO = 37.8 Al2O3 = SiO2 = CaO = FeO = Total = 98.8 Olivine ~ 55 % Orthopyroxene ~ 30 % Clinopyroxene ~ 15 %
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MgO = 37.8 Al2O3 = SiO2 = CaO = FeO = Total = 98.8
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Mg2SiO4 Y / T = 2 MgSiO3 Y / T =1 MgO = 37.8 Al2O3 = SiO2 = CaO = FeO = Total = 98.8
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Ocean Crust Continental Crust Mantle
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? (Mg,Fe)3Al2(SiO4)3 Si = 3/8 or 37.50 Al = 2/8 or 25.00 NaAlSi3O8
MORB ? (Mg,Fe)2SiO4 Si = 1/3 or 33.33 (Mg,Fe)SiO3 Si = 1/2 or 50.00
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Chemical Probes MORB Hot-Spot convecting upper mantle Lower mantle ?
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Source of Modern Hot-Spots ?
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Exchange between the Mantle and Core ?
2(Mg,Fe)OMw FeOliq alloy MgOMw 2(Mg,Fe)SiO3Pv MgSiO3Pv SiO2 + FeOliq alloy (Fe1-x,Mgx)SiO3Pv + 3(1-x)Feliq alloy xMgSiO3Pv + (1-x)FeOliq allo+ (1-x)Fe3Siliq alloy oxidation of the mantle over time? 3Fe2+OMw or Pv Feoliq alloy Fe3+2O3perovskite
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In the beginning ?
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Mg# ~ 0.86
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MORB
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