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Acid/Base Strength 1 1 1 1 1
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How Strong is an Acid? Concentration is always a factor in the strength of an acid, but we’re going to define ‘strength’ by how intrinsically strong or weak the molecule is: HA ⇆ H+ + A- The more this equilibrium favors the products, the stronger the acid is. 2 2 2 2 2
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Strong or Weak? HA ⇆ H+ + A- Strong: Ka > 1
We will just assume all HA becomes products. Strong acids are: HCl (and HBr/HI) HNO3 H2SO HClO4 (rare) 3 3 3 3 3
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Strong or Weak? HA ⇆ H+ + A- Weak: Ka < 1
There is a real equilibrium happening here. Weak acids are: Anything not explicitly strong 4 4 4 4 4
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Strong or Weak? B- + H2O ⇆ HB + OH- Strong: Kb > 1
Again we’ll just assume this goes all the way (100%). Strong bases are: OH-, O2-, H-, and NH2- 5 5 5 5 5
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Strong or Weak? B- + H2O ⇆ HB + OH- Weak: Kb < 1
Again this is a real equilibrium, and there will be ICE box Weak bases are: any base not explicitly strong 6 6 6 6 6
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Conjugate Strengths HA ⇆ H+ + A-
The conjugate base of a strong acid is just not a base (if it goes 100%, then there’s no tendency to go backwards) The conjugate base of a weak acid is a weak base. (the weaker the acid, the stronger the conjugate base) The same applies to bases: the conjugate of a strong base is not an acid. The conjugate of a weak base is a weak acid. 7 7 7 7 7
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