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Physical and Chemical Change
CHAPTER 4 Physical and Chemical Change 4.3 Chemical Reactions in the Lab
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Why would the presence of water on Mars be a sign that life might exist there?
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Why would the presence of water on Mars be a sign that life might exist there?
Many reactions, including those that sustain life, involve chemicals dissolved in water.
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DRY Light blue powder No reaction
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No reaction Chemical reaction DRY IN SOLUTION NaS(aq) CuSO4(aq)
Light blue powder NaS(aq) CuSO4(aq) No reaction Chemical reaction A precipitate is an insoluble compound.
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A solution with water as the solvent is called an aqueous solution.
“Aqua” means “water.” SYMBOLS (s) indicates a solid (l) indicates a liquid (g) indicates a gas (aq) indicates a substance dissolved in water (an aqueous solution)
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O H S O Cu S O 2– 2+ Cu O H A salt is an ionic compound that forms ions when dissolved in water. O H O H
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Can you translate what you see into a chemical equation?
What are the reactants? What are the products?
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Can you translate what you see into a chemical equation?
Cu(s) Zn(s) CuSO4(aq) and Zn(s) is disappearing
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Can you translate what you see into a chemical equation?
Cu(s) Zn(s) CuSO4(aq) and Zn(s) is disappearing a salt in water!
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Can you translate what you see into a chemical equation?
Cu2+(aq) SO42–(aq) Cu(s) Zn(s) + and Zn(s) is disappearing
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Cu2+(aq) SO42-(aq) Cu(s) Zn(s) + and Zn(s) is disappearing Cu2+(aq) e– Cu(s) The copper ion gains 2 electrons to form solid copper. reduction: a chemical reaction that decreases the charge of an atom or ion by accepting electrons.
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Where could those electrons come from?
Cu2+(aq) SO42-(aq) Cu(s) Zn(s) + and Zn(s) is disappearing Cu2+(aq) e– Cu(s) The copper ion gains 2 electrons to form solid copper. Where could those electrons come from?
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Cu2+(aq) + 2e– Cu(s) Zn(s) Zn2+(aq) + 2e–
SO42-(aq) Cu(s) Zn(s) + and Zn(s) is disappearing Cu2+(aq) e– Cu(s) Zn(s) Zn2+(aq) e– Zinc gives up 2 electrons to become a zinc ion, dissolved in water.
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oxidation: a chemical reaction that increases the charge of an atom or ion by giving up electrons.
Zn(s) Zn2+(aq) e– Zinc gives up 2 electrons to become a zinc ion, dissolved in water.
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REACTION NAME Reactants Products Cu2+(aq) e– Cu(s) reduction
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Cu2+(aq) + 2e– Cu(s) reduction Zn(s) Zn2+(aq) + 2e– oxidation
REACTION NAME Reactants Products Cu2+(aq) e– Cu(s) reduction Zn(s) Zn2+(aq) e– oxidation
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To obtain the overall reaction add the reactants, then the products.
REACTION NAME Reactants Products Cu2+(aq) e– Cu(s) reduction Zn(s) Zn2+(aq) e– oxidation These 2 reactions are happening at the same time. To obtain the overall reaction add the reactants, then the products.
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Cu2+(aq) + Zn(s) Cu(s) + Zn2+(aq) redox
REACTION NAME Reactants Products Cu2+(aq) e– Cu(s) reduction Zn(s) Zn2+(aq) e– oxidation Cu2+(aq) Zn(s) Cu(s) Zn2+(aq) redox
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- + H2O OH– + H+ dissociation
The double arrow indicates that the reaction goes in both ways. The heavier arrow means that the reverse reaction is favored.
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Classify these items as acids or bases.
Bases: bathroom cleaner, baking soda Acids: lemon juice, gastric acid
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HCl(l) H+(aq) + Cl–(aq)
Acids give foods like lemons their sour taste. Acids react with metal to create hydrogen gas (H2). Acids can corrode metal and burn skin. Example: H2O(l) HCl(l) H+(aq) Cl–(aq) Hydrochloric acid acid: a chemical that dissolves in water to create more H+ ions than there are in neutral water.
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NaOH(l) Na+(aq) + OH–(aq)
Bases create a bitter taste. Bases have a slippery feel, like soap. Bases can neutralize acids. Example: H2O(l) NaOH(l) Na+(aq) OH–(aq) Sodium hydroxide
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NaOH(l) Na+(aq) + OH–(aq)
Bases create a bitter taste. Bases have a slippery feel, like soap. Bases can neutralize acids. Example: H2O(l) NaOH(l) Na+(aq) OH–(aq) Sodium hydroxide OH–(aq) H+(aq) H2O(l) Result: fewer H+ ions
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NaOH(l) Na+(aq) + OH–(aq)
base: a chemical that dissolves in water to create fewer H+ ions (or more OH– ions)than there are in neutral water. Example: H2O(l) NaOH(l) Na+(aq) OH–(aq) Sodium hydroxide OH–(aq) H+(aq) H2O(l) Result: fewer H+ ions
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Higher H+ concentration Lower H+ concentration
The pH scale helps to determine whether a solution is acidic or basic.
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Higher H+ concentration Lower H+ concentration
A solution with water as the solvent is called an aqueous solution. Redox reactions (transfer of electrons) Acid-base reactions (transfer of protons, H+ ions) two types of chemical reactions that take place in an aqueous environment. Higher H+ concentration Lower H+ concentration
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