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Background [1] A.E. Shilov, G. B. Shul’pin, Chem. Rev. 1997, 97, 2879.
[2] C. M. Jensen, Chem. Commun. 1999, 2443 – 2449. [3] a)A. D. Sadow, T. D. Tilley, Angew. Chem. Int. Ed. 2003, 42, 803. [4] I. A. I. Mkhalid, J. H. Barnard, T. B. Marder, J. M. Murphy, J. F. Hartwig, Chem. Rev. 2010, 110, 890.
![Background [1] A.E. Shilov, G. B. Shul’pin, Chem. Rev. 1997, 97, 2879.](http://slideplayer.com./slide/15090012/91/images/2/Background+%5B1%5D+A.E.+Shilov%2C+G.+B.+Shul%E2%80%99pin%2C+Chem.+Rev.+1997%2C+97%2C+2879..jpg "[2] C. M. Jensen, Chem. Commun. 1999, 2443 – [3] a)A. D. Sadow, T. D. Tilley, Angew. Chem. Int. Ed. 2003, 42, 803. [4] I. A. I. Mkhalid, J. H. Barnard, T. B. Marder, J. M. Murphy, J. F. Hartwig, Chem. Rev. 2010, 110, 890.")
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Background [1] M. P. Doyle, R. Duffy, M. Ratnikov, L. Zhou, Chem. Rev. 2010, 110, 704; [2] H. M. L. Davies, A. R. Dick, Top. Curr. Chem. 2010, 292, 303; [3] D. N. Zalatan, J. Du Bois, Top. Curr. Chem. 2010, 292, 347.
![Background [1] M. P. Doyle, R. Duffy, M. Ratnikov, L. Zhou, Chem. Rev. 2010, 110, 704;](http://slideplayer.com./slide/15090012/91/images/3/Background+%5B1%5D+M.+P.+Doyle%2C+R.+Duffy%2C+M.+Ratnikov%2C+L.+Zhou%2C+Chem.+Rev.+2010%2C+110%2C+704%3B.jpg "[2] H. M. L. Davies, A. R. Dick, Top. Curr. Chem. 2010, 292, 303; [3] D. N. Zalatan, J. Du Bois, Top. Curr. Chem. 2010, 292, 347.")
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Previous work
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Intriguing role of scCO2
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Intriguing role of scCO2
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Comparison
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Factors involved the reaction
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Factors involved the reaction
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“CO2-philicity”
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“CO2-philicity”
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Computation study Self-diffusion activation energy of hexane is 2.18 kcal/mol.
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Outlook Cu “CO2-philicity” and the increasing electrophilicity of the carbene complex Ag diffusion control Utilization of scCO2 Design weak electron donation ligands Design new catalytic system
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