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Review
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Aromatics Which radical is more stable? Draw structures to show stabilization.
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Map out a synthetic route from benzene and/or ethylene.
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Stereochemistry Draw the R and S enantiomers of carvone.
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Label each chiral center as R/S. Which are enantiomer? Diastereomers?
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Which of these compounds are chiral?
2,2,3,3-tetrabromobutane 2,2-dibromo-3,3-dichlorobutane 2,3-dibromo-2,3-dichlorobutane Draw all stereoisomers of the chiral compound and identify the relationships (enantiomers, diastereomers, meso)
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Label each chiral center as R/S. Which are enantiomer? Diastereomers?
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Assign R/S to each chiral center.
Draw sawhorse projections for I and II. Draw skeletal structures for III and IV showing stereochemistry. Identify the stereochemical relationships.
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Map out a synthetic route from ethylene
What is the configuration of each chiral center? Is it the only product formed?
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