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Carbon and the Molecular Diversity of Life
Unit 1 Chapter 4
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Why study Carbon? All living things are made of carbon Cells 72% H2O
3% salts (Na, Cl, K…) 25% carbon compounds carbohydrates lipids proteins nucleic acids
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Tetravalent Electron Configuration
Allows it to make large, complex molecules. Gives covalent compatibility with hydrogen, oxygen, nitrogen, and other carbon atoms. Determines an organic molecule’s 3-dimensional shape
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Hydrocarbons Molecules containing only C and H Nonpolar, hydrophobic
Can undergo reactions that release large amounts of energy EX: methane, fatty acid tails
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Isomers Molecules with same molecular formula but different structures and chemical properties Three Different types: Structural Cis-trans (Geometric) Enantiomers
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Structural Isomers Molecules differ in covalent arrangement of atoms
Same molecular formula but different covalent arrangements
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Cis-trans (geometric)
Molecules differ in arrangement around C=C double bond same covalent partnerships
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Enantiomers Isomers that are mirror images of each other
Important in pharmaceutical industry Enantiomers of Methamphetamine One is drug, other is over the counter in nasal decongestant
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Functional Groups Have specific chemical and physical properties
regions of molecules commonly reactive determine the chemical properties of organic molecules
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Hydroxyl Group -OH Polar Alcohols
Name end in -ol Ethanol Can form hydrogen bonds with water helping dissolve organic compounds
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Carbonyl Group -CO carbon double-bonded to oxygen Called: polar
ketones: carbonyl group is within a carbon skeleton Aldehydes: carbonyl group is at end of carbon skeleton polar found in sugars
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Carboxyl Group -COOH carbon is double-bonded to an oxygen and single-bonded to a hydroxyl group Called: carboxylic acids polar Acts as an acids
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Amino Group NH2 A nitrogen bonded to two hydrogens and carbon skeleton Polar Acts as a base Called amines
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Sulfhydryl Group -SH sulfur bonded to hydrogen are called thiols
Stabilizes the structure of proteins Cross linking of cysteines in hair proteins maintains curliness or straightness. Straight hair can be curled around curlers to break and re from the cross linking bonds
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Phosphate Group -PO4 Phosphate bonded to 4 oxygens Polar
Have potential to react with water releasing energy important in cellular energy storage and transfer (ATP)
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Methyl -CH3 Carbon double bonded to 3 hydrogens
Addition of methyl groups of DNA affects expression
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