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Electron Configuration and Periodic Trends
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Evolution of Atomic Theory
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Dalton’s Atomic Theory
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Dalton’s Atomic Theory
did not explain how atoms break down into subatomic particles
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J.J. Thompson
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found the existence of electrons and created the plum pudding model
J.J. Thompson found the existence of electrons and created the plum pudding model
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Rutherford
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Rutherford discovered the nucleus and proposed the idea of a dense nucleus surrounded by electrons
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Bohr
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Bohr proposed that electrons are arranged in orbits around the nucleus and that the electrons have a fixed energy so they can’t fall into the nucleus
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Quantum Mechanical Model
The modern description of electrons in atoms proposed by Schrödinger
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Quantum Mechanical Model
proposed that the location and energy of an electron could be determined by the Schrödinger wave equation
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Quantum Mechanical Model
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Quantum Mechanical Model
This model tells you that the e is found 90% of the time within a cloud
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Quantum Mechanical Model
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Quantum Mechanical Model and Atomic Orbitals
Principle Quantum Number (n) designates energy levels by n=1,2,3,4….as the electrons move away from the nucleus
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Quantum Mechanical Model and Atomic Orbitals
Sublevels are found within each energy level and they are designated by s, p, d, and f
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Quantum Mechanical Model and Atomic Orbitals
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Quantum Mechanical Model and Atomic Orbitals
Atomic orbitals make up each sublevel
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Quantum Mechanical Model and Atomic Orbitals
Each Atomic orbital holds 2 electrons
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Quantum Mechanical Model and Atomic Orbitals
Chart
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Summary Principle Quantum numbers always equal the number of sublevels within that energy level
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Summary The number of orbitals within each energy level is n2
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Summary The maximum number of electrons that can occupy each energy level is 2n2
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Electron Configuration
The way electrons are arranged around the nucleus of an atom according to the quantum mechanical model Represented by orbital notation
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Electron Configuration
Guidelines: 1. Aufbau Principle Electrons enter orbitals of lowest energy first
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Electron Configuration
2. Pauli Exclusion Principle An atomic orbital at most describes 2 electrons, and they must be of opposite spin
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Electron Configuration
2. Pauli Exclusion Principle
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Electron Configuration
3. Hund’s Rule When electrons occupy orbitals of the same energy, one electron occupies each orbital until all electrons are of the same spin, then second electrons can be added
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Electron Configuration
3. Hund’s Rule
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Electron Configuration
Exceptions to the rules Cu and Cr
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Electron Configuration
Shorthand Notation Energy level (n=1,2,3,…) symbol for sublevel (s, p, d, f) Superscript for electrons Superscripts sum = total electrons
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Electron Configuration
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Electron Configuration
Noble Gas Notation Previous noble gas symbol in brackets Additional orbitals in shorthand
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Electron Configuration
Noble Gas Notation
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