Download presentation
Presentation is loading. Please wait.
Published byMarian Mosley Modified over 6 years ago
1
Consider the Coulomb (J) and resonance integrals (K) in H2+:
What is their contribution to bonding in H2+? They both contribute about equally and favorably. By and large, only K contributes favorably. By and large, only J contributes favorably. None of them contribute favorably.
2
from McQuarrie & Simon “Physical Chemistry”
Consider the Coulomb (J) and resonance integrals (K) in H2+: What is their contribution to bonding in H2+? They both contribute about equally and favorably. By and large, only K contributes favorably. By and large, only J contributes favorably. None of them contribute favorably. from McQuarrie & Simon “Physical Chemistry”
3
What kind of orbital is this?
(A) g u* g* (D) u (E) g* side view view along molecular axis
4
What kind of orbital is this?
(A) g no nodal plane containing the bond ... ; even inversion symmetry ... g no nodal plane between nuclei ... bonding; u* g* (D) u (E) g* side view view along molecular axis
5
What kind of orbital is this?
(A) g u* g* (D) u (E) g* side view view along molecular axis
6
What kind of orbital is this?
(A) g u* no nodal plane containing the bond ... ; odd inversion symmetry ... u nodal plane between nuclei ... antibonding; g* (D) u (E) g* side view view along molecular axis
7
What kind of orbital is this?
(A) g u* g* (D) u (E) g* side view view along molecular axis
8
What kind of orbital is this?
(A) g u* g* one nodal plane containing the bond ... ; even inversion symmetry ... g nodal plane between nuclei ... antibonding; (D) u (E) g* side view view along molecular axis
9
What kind of orbital is this?
(A) g u* g* (D) u (E) g* side view view along molecular axis
10
What kind of orbital is this?
(A) g u* g* (D) u one nodal plane containing the bond ... ; odd inversion symmetry ... u no nodal plane between nuclei ... bonding; (E) g* side view view along molecular axis
Similar presentations
© 2025 SlidePlayer.com. Inc.
All rights reserved.