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Fyzikální principy tvorby nanovláken 11. Kapalinová tryska

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1 Fyzikální principy tvorby nanovláken 11. Kapalinová tryska
D.Lukáš 2010

2 Donghua University, Shanghai, China
Reference: Xiao-Hong Quin & col Donghua University, Shanghai, China Effect of LiCl on electrospinning of PAN polymer solution: theoretical analysis and experimental verification Polymer,

3 z Liquid density Volume flow rate Rovnice kontinuity, zákon zachování hmoty Applied electric field Surface Bulk + + + Rovnice kontinuity pro náboj El. current r u Surface density of the charge + + + Dimensionless conductivity + +

4 Bernoulli equation Zákon zachování energie Electrostatic surface force Viscous force

5 Scaling and dimensionless analysis
mass current Allometric relation energy

6 m=? Nonlinear differential equation

7 z + + + r u + + + + +

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12 Whipping part of the jet

13 a b Figure 4.4. Loops in unstable region of jet, caught on a slide glass -(a) PVA jet, (b) PEO jet.

14 Figure Schematic diagram showing the Pendulum mechanism: (1) ground collector, (2) pendulum and (3) spinning electrode with a polymer.

15 a b Figure 4.5. Instability of Polyethylene-oxide jet - Exposed with two various exposure times of 1 ms and 18 ns.


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