1. Hydrocarbon Derivatives
Amines
Amides
Amino Acids

3. Amines contain N general format: RNH2 NH2 = amino group
N: bonding capacity of 3

4. Properties molecules are polar: boiling points:
H bonding (H bonded to N)
weaker than H-bonding in alcohols & carboxylic acids
H-N weaker than H-O
boiling points:
higher than -anes with same #C’s
lower than alcohols & organic acids with same #C’s
amines smell really, really bad

5. Table R I
1 amines: RNH
2 amines: RNR‘
3 amines: RNR“ H H R’

6. Naming Amines find name of base hydrocarbon
drop -e from -ane ending & add amine
# in front of name indicates C where amino group attached

7. H H H
HCCNH
H H
ethanamine     
H H H H
HCCCNH
H H H    
1-propanamine   

8. < H H H N H HCCCH H H H    2-propanamine    CH2CH2CH2
1,3-propanediamine  
NH2
NH2

9. NH2 
NH2 
CHCH2CH2CH
1,1,4,4-butanetetraamine 
NH2 
NH2

10. Examples of amines
PABA
caffeine
novacain
B-vitamins
dyes

13. Amides amino group bonded to C of carbonyl group
contain 2 functional groups:
carbonyl group (>C=O)
AND
amino group (NH2)
amino group bonded to C of carbonyl group
amides link amino acids together

14. Properties of Amides boiling point:
IMF: hydrogen bonding (N-H)
higher bp than ane with same #C’s
lower bp than alcohols & acids with same #C’s
simple amides are solids at room temp
smaller amides are very soluble in water

15. Table R O = general format: RCNH2 formed through chem reaction:
carboxylic acid: R-COOH
replace the OH with NH2
name: no # needed
amide group is always on end C

16. Naming Amides find name alkane with same # of C’s
drop -e from -ane ending & replace with amide

17. H  O =
HCCNH2
ethanamide  H O =
propanamide
CH3CH2CNH2

20. Amino Acids only need to recognize them do not need to name them
2 functional groups:
contain carboxyl group (-COOH)
AND
contain amino group (-NH2)
amine group on C NEXT to C of carboxyl group

21. amino
acids
NH2  O =
CH3CC 
alanine OH
NH2  O
glycine =
CH2C  OH