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Focus on Covalent bonds types of bonds
Bonding Focus on Covalent bonds types of bonds
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Octet Rule = atoms tend to gain, lose or share electrons so as to have 8 electrons, through the processes of bonding
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Metallic Bonds Formed between atoms of metallic elements
Electron cloud around atoms Strong bonds Good conductors at all states, lustrous, very high melting points Examples; Na, Fe, Al, Au, Co Metals do not combine with metals. They form Alloys which is a solution of a metal in a metal. Examples are steel, brass, bronze and pewter.
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Metallic Bonds: Mellow dogs with plenty of bones to go around.
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Review: Ionic Bonds Ionic compounds result when metals react with nonmetals Metals lose electrons to match the number of valence electrons of their nearest noble gas Positive ions form when the number of electrons are less than the number of protons Group 1 metals ion 1+ Group 2 metals ion 2+ Group 13 metals ion 3+
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Review: Ionic Bonds Between atoms of metals and nonmetals with very different electronegativity Bond formed by transfer of electrons Produce charged ions all states. Conductors and have high melting point. Examples; NaCl, CaCl2, K2O
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Salt versus Molecules A metal cation and nonmetal anion are joined together by an ionic bond called SALT A group of atoms joined together by a covalent bond is called a MOLECULE A Compound is a group of two or more elements bonded together (Ionic or Covalent).
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Monatomic vs. Diatomic Molecules
Most molecules can be monatomic or diatomic Diatomic Molecule is a molecule consisting of two atoms There are 7 diatomic molecules (SUPER 7) – N2, O2, F2, Cl2, Br2, I2, H2 You can also remember them as: H2O2F2Br2I2N2Cl2
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Properties of Molecular Compounds
Liquids or gases at room temperature Lower Melting Points than Ionic Compounds (which means that they are weaker than ionic)
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Ionic Compounds Molecular Compounds Crystal Lattice Molecule Types of Elements Metal with non-metal or polyatomic ions Non-metal with non-metal Physical State Solid Solid, liquid or gas Melting Point High > 300 C Low <300 C Solubility in water Generally high Generally low Electrical conductivity of solution Good conductor Poor to none
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Covalent Bond Between nonmetallic elements of similar electronegativity. Formed by sharing electron pairs Stable non-ionizing particles, they are not conductors at any state Examples; O2, CO2, C2H6, H2O, SiC
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Two Types of Covalent bonds
Polar Covalent Non-polar Covalent
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Polar Covalent
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Non- polar Covalent
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How do we determine bond type
Bond character can be predicted by subtracting the electronegativities of the two atoms involved in the bond. Nonpolar covalent bond-difference of less than 0.5 Polar covalent bond-difference of Ionic bond-difference of more than 2.1
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Molecule A neutral group of atoms joined together by covalent bonds.
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Diatomic Molecules Molecules made up of two atoms.
There are 7 diatomic molecules. H2, N2, O2, F2, Cl2, Br2, I2
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Hydrogen Hydrogen Hydrogen
H· ·H H:H Hydrogen Hydrogen Hydrogen Atom Atom molecule The hydrogen molecule has a single covalent bond. The electronegativity of each hydrogenatom is the same, so the electrons are shared. Shared electron pair
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Ionic Compounds Molecular Compounds Crystal Lattice Molecule Types of Elements Metal with non-metal or polyatomic ions Non-metal with non-metal Physical State Solid Solid, liquid or gas Melting Point High > 300 C Low <300 C Solubility in water Generally high Generally low Electrical conductivity of solution Good conductor Poor to none
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Polar molecules have a positive end and a negative end.
A molecule for which this is true is a dipole. The strength of this polarity is measured by the dipole moment. The higher the dipole moment, the higher the polarity. As the polarity of the molecule increases, so does its bond strength.
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Naming binary covalent compounds
Table 6-5 on p. 212 gives the prefixes used in naming covalent compounds. The first element named is usually the first one written in the formula-the least electronegative element The root word is the name of the element. The prefix is used to indicate how many atoms of that element are in the molecule. The prefix mono- is not used in the first word of the name.
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Naming binary covalent compounds
The last element in the compound is generally the element with the higher electronegativity. It is given the suffix –ide, just as in binary ionic compounds. The prefix is used to indicate how many atoms of that element are in the molecule. The prefix mono- is used for the second element when only one atom of that element is present.
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Example: CO There is only one carbon. Since carbon is the first element, the prefix mono- is not used. There is only one oxygen, but since this is the second element, the prefix mono- is used. Because oxygen is the second element, we add the suffix -ide. The name of this compound is: Carbon monoxide
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Example: P4O6 There is are 4 phosphorus atoms in this compound. The prefix for 4 is tetra-. There are 6 oxygen atoms in this compound. The prefix for 6 is hexa-. Because oxygen is the second element, we add the suffix -ide. The name of this compound is: Tetraphosphorus hexoxide
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