1. Volume 3, Issue 1, Pages 174-191 (July 2017)
Artificial Chiral Metallo-pockets Including a Single Metal Serving as Structural Probe and Catalytic Center 
Pinglu Zhang, Coralie Tugny, Jorge Meijide Suárez, Maxime Guitet, Etienne Derat, Nicolas Vanthuyne, Yongmin Zhang, Olivia Bistri, Virginie Mouriès-Mansuy, Mickaël Ménand, Sylvain Roland, Louis Fensterbank, Matthieu Sollogoub 
Chem 
Volume 3, Issue 1, Pages (July 2017)
DOI: /j.chempr
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2. Chem 2017 3, DOI: ( /j.chempr )
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3. Figure 1
Representation of a Carbene-Capped Cyclodextrin Metal Complex Characterized by a Well-Defined Placing of the Metal Inside the Cavity
The carbene (NHC) is represented in blue. The cyclodextrin macrocycle is shown in beige.
Chem 2017 3, DOI: ( /j.chempr )
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4. Figure 2 Presentation of All Carbene-Capped CDs Studied
Chem 2017 3, DOI: ( /j.chempr )
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5. Figure 3 NCI Analysis of (α-ICyD)AgCl
The molecular structure is displayed by the yellow backbone, and the NCI layers are color coded as follows: blue, strong interactions; green, weak interactions; and red, repulsive interactions. (1) Anagostic interactions between H-5s and Ag, green circles; (2) weak hydrogen bonds between H-3s and Cl, red circles.
Chem 2017 3, DOI: ( /j.chempr )
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6. Figure 4 Superimposition of Modeled (α-ICyD)AgCl
DFT, green; molecular mechanics, blue.
Chem 2017 3, DOI: ( /j.chempr )
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7. Figure 5
Models of (α-ICyD)AgCl, (β-ICyD)AgCl, (α-TriCyD)AgCl, (γ-A,E-ICyD)AgCl, and (γ-A,D-ICyD)AgCl
Ag to H-5s distances (in green) and Cl to H-3s distances (in red) are ordered according to their chemical shifts.
Chem 2017 3, DOI: ( /j.chempr )
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8. Figure 6
Estimated Average Shapes, Connolly Surface, in Solutions of (α-ICyD)MCl, (β-ICyD)MCl, (α-TriCyD)MCl, (γ-A,E-ICyD)MCl, and (γ-A,D-ICyD)MCl
Arrows indicate the groove, the narrow side, or the M-helix side. Cl has been omitted for clarity. Me groups are oriented in the same direction for comparison purposes.
Chem 2017 3, DOI: ( /j.chempr )
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9. Figure 7
Rationalization of the Enantioselectivities in the Cycloisomerization of 6
(A) Possible approaches of 6 on (α-ICyD)Au. The sterically favored approach is in green, and the sterically unfavored approach is in red.
(B) The corresponding simplified model.
(C) Possible approaches of 6 on (β-ICyD)Au. The sterically favored approach is in green, and the sterically unfavored approach is in red.
(D) The corresponding simplified model.
Chem 2017 3, DOI: ( /j.chempr )
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10. Scheme 1 General Synthetic Scheme
Chem 2017 3, DOI: ( /j.chempr )
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11. Scheme 2 Gold-Catalyzed Regioselective Cycloisomerization of Enyne 1
Chem 2017 3, DOI: ( /j.chempr )
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12. Scheme 3
Proposed Mechanism of the Gold-Catalyzed Regioselective Cycloisomerization of Enyne 1 Using α-ICyD
Chem 2017 3, DOI: ( /j.chempr )
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13. Scheme 4
Proposed Mechanism of the Gold-Catalyzed Regioselective Cycloisomerization of Enyne 1 Using β-ICyD
Chem 2017 3, DOI: ( /j.chempr )
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14. Scheme 5
Gold-Catalyzed Enantioselective Cycloisomerizations of Enynes 5 and 6
Chem 2017 3, DOI: ( /j.chempr )
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