1. Drill and Practice makes me happy !

2. Almost the last Drill and Practice: Reactions of Aldehydes and Ketones
Strongest oxidizer=
oxidizer
KMnO4
Medium strength oxidizer=
K2Cr2O7
Can be any RCHO
Weakest oxidizer=
Ag2O/NH3
KMnO4/HIO4

3. H+ Wittig reaction Upper reaction (thru LiAlH4,H+) With forms: +
The Almost Final Drill and Practice: Reactions of Aldehydes and Ketones (cont.) +
Name of this route to larger alkenes ?
Wittig reaction
Product by-product H+
Upper reaction (thru LiAlH4,H+)
With forms:

4. + HCl + Name of the above oxidation ? By-product Product
The Almost Final Drill and Practice: Reactions of Aldehydes and Ketones (cont.)
Route to peroxy acid +
Name of the above oxidation ?
By-product
Product
Baeyer-Villiger
HCl +
Weird name of product
ylide
Product By-product

5. H2O + 2 Acetic Acid (solvent) +
The Almost Final Drill and Practice: Reactions of Aldehydes and Ketones (cont.)
Acetic Acid
(solvent) + + 2
H2O

6. H2O H2O + immine + enamine Class name of product ? Product by- product
The Almost Final Drill and Practice: Reactions of Aldehydes and Ketones (cont.)
H2O +
Class name of product ?
immine
Product by- product +
H2O
Product by- product
enamine
Class name of product ?
Hint: an alpha H substitution

7. The Almost Final Drill and Practice: Reactions of Aldehydes and Ketones (cont.)
hint
+ H2O
Reaction name ? (You did one in lab…)
Aldol condensation (aldehyde to bigger alcohol bigger alkene) +

9. Organic is almost
over !!