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Chapter 3 Chem 341 Suroviec Fall 2016
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I. Water Nearly all biomolecules assume their shape due to water Polar Molecule Central oxygen forms covalent bonds with two hydrogen atoms, leaving 2 unshared electrons
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B. Types of Interactions
Non-covalent interactions Ionic Hydrogen-bonds Dipole-dipole Dipole-induced dipole London dispersion
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Table 2-1
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C. Hydrophobic, Hydrophilic and Amphiphillic
Water sticks together Non-polar sticks together Affects entropy Hydrophilic Polar water will dissolve ionic and polar substances Amphophilic Polar and Nonpolar Forms micelles and bicelles
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II Properties of Water Polar Molecule High heat of vaporization C. High heat capacity D. High melting/boiling point
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III. Chemical Properties
Water as a solvent Ability to form H-bonds B. Hydrophobic effect Nonpolar substance does not dissolve but phase separates
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IV. Acids, Bases and pH Water ionization 2. pH of a solution
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D. Acids, Bases and pH Acid dissociation Base dissociation
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D. Acids, Bases and pH 5. pka = -log Ka Acids are classified by Ka Weak acids: Ka < 1 (partially dissociated) Strong acids: Ka >1 (completely dissociated)
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D. Acids, Bases and pH Buffers Conjugate acid/base combination that over a small pH range resists changes in pH
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D. Acids, Bases and pH
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