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CHARLES’ LAW A gas in a closed system at a constant pressure, the temperature and the volume are directly proportional.
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CHARLES’ LAW Directly proportional means that as the temperature increases, the volume increases. Or as the temperature decreases the volume decreases. Mathematically: V1 V T1 T2
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CHARLES’ LAW The balloon in the picture has a volume of 0.5 liters at a room temperature of 22oC. What will the volume of the balloon be if put into some liquid nitrogen? The liquid nitrogen is at -196oC.
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KELVIN Before doing anything, you must convert the temperatures to the Kelvin scale. K = C +273 K = = 295 K K = = 77 K Now you can plug the numbers into the Charles’ law equation.
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The volume goes down, down, down!
0.5 L V2_ 295 K 77 K Cross Multiply 295 V2 = 38.5 V2 = 0.13 liters
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Practice Makes Perfect
Practice Problem #1: A container with a volume of 148ml is at standard temperature. If the container is heated to 500 K, what is the new volume? Standard Temperature: 0oC = 273 K Practice problem #2: A syringe is set at 7ml at a pressure of 25oC. If the volume is increased to 9ml, what is the new temperature? Work these problems on your paper and then check your answer.
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How did you do? Practice problem #1, the answer is 271ml
Practice problem #2, the answer is 110oC. (To get the correct answer, you had to convert 25oC to 298 K, the answer is also 383K) Practice problem #3: A basketball is inflated to 3.5 liters with an air temperature of 40oC. When the basketball is taken outside, the volume drops to 3.1 liters. What is the temperature outside?
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Now it is time to move on to DALTON’S LAW
The answer is 4oC Now it is time to move on to DALTON’S LAW
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The sum of the partial pressures is equal to the total pressure.
DALTON’S LAW The sum of the partial pressures is equal to the total pressure.
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DALTON’S LAW The two containers have equal volume.
The containers are connected by a hose, but the valve is closed.
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DALTON’S LAW The container on the left has a pressure of 500mm Hg.
The container on the right has a pressure of 300mm Hg
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DALTON’S LAW P1 + P2 + … = Ptotal
If all of the gas from the left container is pushed into the right container, what is the total pressure of the gas? P1 + P2 + … = Ptotal
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DALTON’S LAW The total pressure is now 800 mmHg.
The sum of the partial pressures is equal to the total pressure. Let’s try one practice problem.
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P1 + P2 + … = Ptotal A 2 liter container has a gas with a pressure of 1.04 atm. Another 2 liter container has a gas with a pressure of 760mm Hg. If the two containers are combined into one 2 liter container, what is the total pressure? Hint: Be consistent with units.
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2.04 atm The easiest way to solve this problem is to convert 760mm Hg to 1atm. From there, it is simple: 1.04atm + 1atm = 2.04atm
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