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Ch. 10: Physical Properties of Gases
10.3 Gas Laws: Relationships between volume, temperature, pressure, and amount of gas.
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Boyle’s Law: P and V as one increases, the other decreases
inversely proportional pressure is caused by moving molecules hitting container walls
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Boyle’s Law: P and V Boyle’s Law: the V of fixed mass of gas varies inversely with P at a constant T. What kind of graph is V vs. P?
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Boyle’s Law
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Example: Boyle’s Law Consider a 1.53-L sample of gaseous SO2 at a pressure of 5.6 x 103 Pa. If the pressure is changed to 1.5 x 104 Pa at constant temperature, what will be the new volume of the gas?
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Charles’ Law: V and T if P is constant, gases expand when heated
when T increases, gas molecules move faster and collide with the walls more often and with greater force to keep the P constant, the V must increase
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Charles’ Law: V and T Problem: if we use Celsius, we could end up with negative values from calculations in gas laws for volumes we need a T system with no negative values: Kelvin Temperature Scale starts at ° C = absolute zero = 0 K lowest possible temperature
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Charles’ Law: V and T Charles’ Law: the V of fixed mass of gas at constant P varies directly with Kelvin T. What kind of graph is V vs. T?
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Charles’ Law discovered by French physicist, Jacques Charles in 1787
first person to fill balloon with hydrogen gas and make solo balloon flight
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Example: Charles’ Law A sample of gas at 15°C and 1 atm has a volume of 2.58 L. What volume will this gas occupy at 38°C and 1 atm?
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