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Strongly Binding Ligands Cause the Carbene Fragment to be Lost as a Phosphorus Ylide Isocyanide ligand binds to ruthenium and sweeps away the carbene fragment.

Published byἈρταξέρξης Παπακώστας Modified over 6 years ago

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Presentation on theme: "Strongly Binding Ligands Cause the Carbene Fragment to be Lost as a Phosphorus Ylide Isocyanide ligand binds to ruthenium and sweeps away the carbene fragment."— Presentation transcript:

1 Strongly Binding Ligands Cause the Carbene Fragment to be Lost as a Phosphorus Ylide
Isocyanide ligand binds to ruthenium and sweeps away the carbene fragment The rapid loss of carbenic activity stops metathesis with this first generation Grubbs complex “Isocyanide-Promoted Ylidene Transfer to Phosphorus: Rearrangement in the First Generation Grubbs Complex” Galan, B. R.; Pitak, M.; Keister, J. B.; Diver, S. T. Organometallics 2008, 27, ; We gratefully acknowledge support of this work by the ACS-PRF through research grant AC1 to Diver and Keister.

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