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HOW DO WE KNOW A CHEMICAL CHANGE/REACTION HAS OCCURRED?
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let’s go to one of the old classics
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BAKING SODA & VINEGAR (ACETIC ACID) REACTION
NaHCO3 + HC2H3O2 NaC2H3O2 + H2O + CO2 BAKING SODA ACETIC ACID (VINEGAR) SODIUM ACETATE WATER CARBON DIOXIDE REACTANTS PRODUCTS
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BAKING SODA & VINEGAR (ACETIC ACID) REACTION
What gas is produced? BAKING SODA & VINEGAR (ACETIC ACID) REACTION NaHCO3 + HC2H3O2 NaC2H3O2 + H2O + CO2 BAKING SODA VINEGAR SODIUM ACETATE WATER CARBON DIOXIDE REACTANTS PRODUCTS
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BAKING SODA & VINEGAR (ACETIC ACID) REACTION
What gas is produced? CO2 BAKING SODA & VINEGAR (ACETIC ACID) REACTION NaHCO3 + HC2H3O2 NaC2H3O2 + H2O + CO2 BAKING SODA VINEGAR SODIUM ACETATE WATER CARBON DIOXIDE REACTANTS PRODUCTS
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does carbon dioxide fuel a fire?
Does FIRE need CO2?
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does carbon dioxide fuel a fire?
Does FIRE need CO2? As a REACTANT? NO!!!
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does carbon dioxide fuel a fire?
Does FIRE need CO2? NO!!! OXYGEN FUELS A FIRE!
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See how oxygen gas (O2) is a reactant in all of these…
4Fe + 3O2 à 2Fe2O3 C3N6H6O6 + O2 3 CO2 + 2 H2O + 3 N2 + H2 2CH2 + 3O2 à 2CO2 + 2H2O 2C4H O2 à 8CO2 + 10H2O COMBUSTION & CORROSION NEED OXYGEN AS A REACTANT– THEREFORE, WE CALL THESE OXIDATION REACTIONS
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Which one is the rusting/corroding of iron?
4Fe + 3O2 à 2Fe2O3 C3N6H6O6 + O2 3 CO2 + 2 H2O + 3 N2 + H2 2CH2 + 3O2 à 2CO2 + 2H2O 2C4H O2 à 8CO2 + 10H2O COMBUSTION & CORROSION NEED OXYGEN AS A REACTANT– THEREFORE, WE CALL THESE OXIDATION REACTIONS
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Which reaction seems to be the most sensitive/tempermental?
4Fe + 3O2 à 2Fe2O3 IRON RUSTING/CORRODING C3N6H6O6 + O2 3 CO2 + 2 H2O + 3 N2 + H2 2CH2 + 3O2 à 2CO2 + 2H2O 2C4H O2 à 8CO2 + 10H2O COMBUSTION & CORROSION NEED OXYGEN AS A REACTANT– THEREFORE, WE CALL THESE OXIDATION REACTIONS
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Which one needs the least oxygen to make the most products?
4Fe + 3O2 à 2Fe2O3 IRON RUSTING/CORRODING C3N6H6O6 + O2 3 CO2 + 2 H2O + 3 N2 + H2 2CH2 + 3O2 à 2CO2 + 2H2O 2C4H O2 à 8CO2 + 10H2O COMBUSTION & CORROSION NEED OXYGEN AS A REACTANT– THEREFORE, WE CALL THESE OXIDATION REACTIONS
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That second reaction is the combustion/explosion of c4!!!
4Fe + 3O2 à 2Fe2O3 IRON RUSTING/CORRODING C3N6H6O6 + O2 3 CO2 + 2 H2O + 3 N2 + H2 C4 EXPLOSION 2CH2 + 3O2 à 2CO2 + 2H2O 2C4H O2 à 8CO2 + 10H2O COMBUSTION & CORROSION NEED OXYGEN AS A REACTANT– THEREFORE, WE CALL THESE OXIDATION REACTIONS
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The last 2 are the combustion reactions for wax and butane.
4Fe + 3O2 à 2Fe2O3 IRON RUSTING/CORRODING C3N6H6O6 + O2 3 CO2 + 2 H2O + 3 N2 + H2 C4 EXPLOSION 2CH2 + 3O2 à 2CO2 + 2H2O CANDLE WAX BURNING 2C4H O2 à 8CO2 + 10H2O BUTANE LIGHTER COMBUSTION & CORROSION NEED OXYGEN AS A REACTANT– THEREFORE, WE CALL THESE OXIDATION REACTIONS
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COMBUSTION & CORROSION NEED
If were on a submarine undersea, and you had only candles and butane to keep you warm, which would you use? 4Fe + 3O2 à 2Fe2O3 IRON RUSTING/CORRODING C3N6H6O6 + O2 3 CO2 + 2 H2O + 3 N2 + H2 C4 EXPLOSION 2CH2 + 3O2 à 2CO2 + 2H2O CANDLE WAX BURNING 2C4H O2 à 8CO2 + 10H2O BUTANE LIGHTER COMBUSTION & CORROSION NEED OXYGEN AS A REACTANT– THEREFORE, WE CALL THESE OXIDATION REACTIONS
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COMBUSTION & CORROSION NEED
If we’re on a submarine undersea, candles uses up less oxygen in its reaction. 4Fe + 3O2 à 2Fe2O3 IRON RUSTING/CORRODING C3N6H6O6 + O2 3 CO2 + 2 H2O + 3 N2 + H2 C4 EXPLOSION 2CH2 + 3O2 à 2CO2 + 2H2O CANDLE WAX BURNING 2C4H O2 à 8CO2 + 10H2O BUTANE LIGHTER COMBUSTION & CORROSION NEED OXYGEN AS A REACTANT– THEREFORE, WE CALL THESE OXIDATION REACTIONS
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oxygen helps rust, combust, fire-up & explode!!!
4Fe + 3O2 à 2Fe2O3 IRON RUSTING C3N6H6O6 + O2 3 CO2 + 2 H2O + 3 N2 + H2 C4 EXPLOSION 2CH2 + 3O2 à 2CO2 + 2H2O CANDLE WAX BURNING 2C4H O2 à 8CO2 + 10H2O BUTANE LIGHTER COMBUSTION & CORROSION NEED OXYGEN AS A REACTANT– THEREFORE, WE CALL THESE OXIDATION REACTIONS
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DUMB QUESTION: ARE OXIDATION REACTIONS EXO OR ENDOTHERMIC?
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COMBUSTION & CORROSION NEED
oxygen helps rust, combust, fire-up & explode! OXIDATION REACTIONS ARE EXOTHERMIC 4Fe + 3O2 à 2Fe2O3 IRON RUSTING C3N6H6O6 + O2 3 CO2 + 2 H2O + 3 N2 + H2 C4 EXPLOSION 2CH2 + 3O2 à 2CO2 + 2H2O CANDLE WAX BURNING 2C4H O2 à 8CO2 + 10H2O BUTANE LIGHTER COMBUSTION & CORROSION NEED OXYGEN AS A REACTANT– THEREFORE, WE CALL THESE OXIDATION REACTIONS
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To stop oxidation/combustion reactions, we shut off the supply of ________ gas reactant.
Fire extinguishers either release water or carbon dioxide foam. Blanket or covering a fire stops the oxygen from reaching the flame.
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To stop oxidation/combustion reactions, we shut off the supply of oxygen gas reactant.
Fire extinguishers either release water or carbon dioxide foam. Blanket or covering a fire stops the oxygen from reaching the flame.
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COMBUSTION & CORROSION NEED reactant, the whole reaction STOPS!
oxygen helps rust, combust, fire-up & explode! OXIDATION REACTIONS ARE EXOTHERMIC 4Fe + 3O2 à 2Fe2O3 IRON RUSTING C3N6H6O6 + O2 3 CO2 + 2 H2O + 3 N2 + H2 C4 EXPLOSION 2CH2 + 3O2 à 2CO2 + 2H2O CANDLE WAX BURNING 2C4H O2 à 8CO2 + 10H2O BUTANE LIGHTER COMBUSTION & CORROSION NEED OXYGEN without oxygen gas as a reactant, the whole reaction STOPS!
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Check for understanding…
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Which gas can STOP combustion?
OXYGEN GAS (O2) CARBON DIOXIDE (CO2)
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Which gas can STOP combustion?
CARBON DIOXIDE (CO2) OXYGEN GAS (O2) OMG…this STARTS the whole thing!!!
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What’s a heavier molecule: CO2 or O2?
Which has more atomic mass?
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What’s a heavier molecule: CO2 or O2?
Use your periodic tables!!!
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COMPARE MOLECULAR MASS!
CARBON DIOXIDE OXYGEN GAS 16+16
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Carbon dioxide CO2 is a heavier molecule!
OXYGEN GAS = 44 16+16 = 32
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Anyways…
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Let’s compare Compare reactions:
Vinegar & baking soda reaction NaHCO3 + HC2H3O2 NaC2H3O2 + H2O + CO2 Candle wax burning reaction 2CH2 + 3O2 à 2CO2 + 2H2O
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What if I replaced the O2 reactant in the candle burning reaction with CO2?
Vinegar & baking soda reaction NaHCO3 + HC2H3O2 NaC2H3O2 + H2O + CO2 Candle wax burning reaction 2CH2 + 3O2 à 2CO2 + 2H2O
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What if I replaced the O2 reactant in the candle burning reaction with CO2?
Vinegar & baking soda reaction NaHCO3 + HC2H3O2 NaC2H3O2 + H2O + CO2 Candle wax burning reaction 2CH2 + 3O2 à 2CO2 + 2H2O The reaction would stop & the flame would go out!
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Where can I get a whole lot of carbon dioxide to find out!
That old classic reaction that’s where!
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BAKING SODA & VINEGAR (ACETIC ACID) REACTION
YES!!! BAKING SODA & VINEGAR (ACETIC ACID) REACTION NaHCO3 + HC2H3O2 NaC2H3O2 + H2O + CO2 BAKING SODA VINEGAR SODIUM ACETATE WATER CARBON DIOXIDE REACTANTS PRODUCTS
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And we Know now that CO2 is a heavier gas compared to O2!
That old classic reaction that’s where!
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CO2 pours into the beaker & replaces the O2 reactant in the candle reaction.
Vinegar & baking soda reaction NaHCO3 + HC2H3O2 NaC2H3O2 + H2O + CO2 Candle wax burning reaction 2CH2 + 3O2 à 2CO2 + 2H2O The reaction stops & the flame goes out!
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CO2 pours into the beaker & replaces the O2 reactant in the candle reaction.
Vinegar & baking soda reaction NaHCO3 + HC2H3O2 NaC2H3O2 + H2O + CO2 Candle wax burning reaction 2CH2 + 3O2 à 2CO2 + 2H2O The reaction stops & the flame goes out!
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replace the O2 reactant WITH HEAVIER CO2 SHUTS DOWN THE REACTION!.
Vinegar & baking soda reaction NaHCO3 + HC2H3O2 NaC2H3O2 + H2O + CO2 Candle wax burning reaction 2CH2 + 3O2 à 2CO2 + 2H2O The reaction stops & the flame goes out!
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How did we know the baking soda reacted with the vinegar?
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EVIDENCE of a CHEMICAL REACTION (aka a CHEMICAL CHANGE)
1. 2. a. b
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EVIDENCE of a CHEMICAL REACTION (aka a CHEMICAL CHANGE)
a GAS is produced (fizzes up)
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How did we know the candle burning was a combustion chemical reaction?
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EVIDENCE of a CHEMICAL REACTION (aka a CHEMICAL CHANGE)
a GAS is produced a TEMPERATURE change
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Some chemical reactions RELEASE heat!
W_ _ m pack, butane l_ _ _ter, c_ _dle, f_ _ewor_ _,
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Some chemical reactions RELEASE heat!
Warm pack, butane lighter, candle, fireworks,
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SIGNS of a CHEMICAL REACTION (aka a CHEMICAL CHANGE)
a GAS is produced a TEMPERATURE change temp heat EXITS reaction--EXOTHERMIC
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Heat is released during EXOTHERMIC chemical reactions.
Candle wax burning reaction 2CH2 + 3O2 à 2CO2 + 2H2O + HEAT Hand warmers 4Fe + 3O2 2Fe2O3 + heat Potassium permagneate & glycerin 14 KMnO4 + 4 C3H5(OH)3 7K2CO3 + 7Mn2O3 + 5CO2 + 16H2O + HEAT
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How about PHOTOSYNTHESIS
How about PHOTOSYNTHESIS? Do phytoplankton and trees release OR absorb heat?
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With PHOTOSYNTHESIS, phytoplankton and trees ABSORB the SUN’s heat
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That’s partly why its cooler to lay on your lawn than on your driveway during the summer!
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trees absorb heat when doing photosynthesis
That’s why its cooler to walk through the shaded forest than a shaded garage. trees absorb heat when doing photosynthesis
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SIGNS of a CHEMICAL REACTION (aka a CHEMICAL CHANGE)
a GAS is created as a product a TEMPERATURE change temp heat EXITS reaction—EXOTHERMIC temp heat ENTERS reaction-ENDOthermic
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Can you think of any ENDOthermic reactions that cool thing down in your home?
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FRIDGES & AIR CONDITIONERS USE ENDOTHERMIC REACTIONS.
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Check out this ENDOthermic reaction!
Barium hydroxide (Ba(OH)2) mixed with ammonium chloride (NH4Cl)… HEAT + Ba(OH)2 + 8 H2O + 2 NH4Cl → 2 NH H2O + BaCl2
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Some reactions ABSORB heat!
Barium hydroxide (Ba(OH)2) mixed with ammonium chloride (NH4Cl)… HEAT + Ba(OH)2 + 8 H2O + 2 NH4Cl → 2 NH H2O + BaCl2 COLD PACK! REFRIDGERATORS! PHOTOSYNTHESIS!!!
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what other signs do we have that a chemical reaction/change has occurred????
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SIGNS of a CHEMICAL REACTION (aka a CHEMICAL CHANGE)
a GAS is created as a product a TEMPERATURE change temp heat EXITS reaction—EXOTHERMIC temp heat ENTERS reaction-ENDOthermic A ??????????????change
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A BIG _ _ _ _ _ change is an OBVIOUS sign of chemical reaction & change.
_ _ _ _ _ change indicates a new substances has been formed… first 1:14 of then 7:25-8:10
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SIGNS of a CHEMICAL REACTION (aka a CHEMICAL CHANGE)
a GAS is created as a product a TEMPERATURE change temp heat EXITS reaction—EXOTHERMIC temp heat ENTERS reaction-ENDOthermic a DRAMATIC COLOR change
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Sulfuric acid helps oxidizing sugar shows all 4 signs of a chemical change…BUT ESPECIALLY COLOR CHANGE! C12H22O O CO2 + 8 C + 11 H2O H2SO4
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Sulfuric acid helps oxidizing sugar shows all 4 signs of a chemical change…BUT ESPECIALLY COLOR CHANGE! What role does sulfuric acid H2SO4 play in this chemical reaction? C12H22O O CO2 + 8 C + 11 H2O H2SO4
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Sulfuric acid helps oxidizing sugar shows all 4 signs of a chemical change…BUT ESPECIALLY COLOR CHANGE! What role does sulfuric acid H2SO4 play in this chemical reaction? C12H22O O CO2 + 8 C + 11 H2O CATALYST H2SO4
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Behold the GLOW STICK reaction!
C14H10O4 + H2O __C6H6O + C2O4
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How many molecules of C6H6O do we make here?
C14H10O4 + H2O __C6H6O + C2O4
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Behold the GLOW STICK reaction!
C14H10O4 + H2O C6H6O + C2O4
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A BIG color change is an OBVIOUS sign of chemical reaction & change.
Color change indicates a new substances has been formed… first 1:14 of then 7:25-8:10
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SIGNS of a CHEMICAL REACTION (aka a CHEMICAL CHANGE)
a GAS is created as a product a TEMPERATURE change temp heat EXITS reaction—EXOTHERMIC temp heat ENTERS reaction-ENDOthermic a DRAMATIC COLOR change WHAT’S THE LAST SIGN?????
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corroded batteries and pennies…
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SIGNS of a CHEMICAL REACTION (aka a CHEMICAL CHANGE)
a GAS is created as a product a TEMPERATURE change temp heat EXITS reaction—EXOTHERMIC temp heat ENTERS reaction-ENDOthermic a DRAMATIC COLOR change a PRECIPITATE forms
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But what is a PRECIPITATE?
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Batteries are chemical reactions inside a metal shell or plastic box
Batteries are chemical reactions inside a metal shell or plastic box. When these reactions occur, often we get a precipitate.
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SIGNS of a CHEMICAL REACTION (aka a CHEMICAL CHANGE)
a GAS is created as a product a TEMPERATURE change temp heat EXITS reaction—EXOTHERMIC temp heat ENTERS reaction-ENDOthermic a DRAMATIC COLOR change a PRECIPITATE forms WHEN REACTANTS TURN INTO NEW SOLID PRODUCTS
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nylon rope demo
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END onto blue lab
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