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Weak Acids
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Question Is it possible for a strong acid solution and a weak acid solution to have the same pH?
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Weak Acids are in Equilibrium
HX(aq) H+ + X- Ka = [H+][X-] [HX] Ka – acid-dissociation constant
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Example A student prepared a .10M solution of formic acid (HCHO2) and measured its pH to be A) calculate the Ka B) What is the % of the acid dissociated?
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Example Calculate the pH of a .20M solution of HCN whose Ka = 4.9 x 10-10
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Example Calculate the % HF ionized in a .10M HF solution. Ka = 6.8 x 10-4
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Polyprotic Acid Acids capable of furnishing more than one proton
H2SO4 H+ + HSO4- Ka1 = 1.7x10-2 HSO4- H+ + SO Ka2 = 6.4x10-8 If difference in Ka1 and Ka2 is > 103 only need to consider Ka1
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Example A solution of .0037M H2CO3 dissociates in water. What is the approximate pH of the solution?
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