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Dimensional Analysis, Significant Figures, & the Metric System
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Accuracy vs. Precision ACCURATE = CORRECT PRECISE = CONSISTENT
Accuracy - how close a measurement is to the accepted value Precision - how close a series of measurements are to each other ACCURATE = CORRECT PRECISE = CONSISTENT
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Percent Error your value accepted value
Indicates accuracy of a measurement your value accepted value
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Percent Error Example % error = 2.9 %
A student determines the density of a substance to be 1.40 g/mL. Find the % error if the accepted value of the density is 1.36 g/mL. % error = 2.9 %
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Significant Figures Indicates precision of a measurement.
Counting Sig Figs Count all numbers EXCEPT: Leading zeros Trailing zeros without a decimal point -- 2,500
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Counting Significant Figures
4 sig figs 3 sig figs 3. 5,280 3. 5,280 3 sig figs 2 sig figs
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Calculating Significant Figures
Multiply/Divide - The # with the fewest sig figs determines the # of sig figs in the answer. (13.91g/cm3)(23.3cm3) = g 4 SF 3 SF 3 SF 324 g
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Calculating Significant Figures (cont’d.)
Add/Subtract - The # with the lowest decimal value determines the place of the last sig fig in the answer. 3.75 mL mL 7.85 mL 3.75 mL mL 7.85 mL 224 g + 130 g 354 g 224 g + 130 g 354 g 7.9 mL 350 g
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Scientific Notation 65,000 kg 6.5 × 104 kg
Converting into Sci. Notation: Move decimal until there’s 1 digit to its left. Places moved = exponent. Large # (>1) positive exponent (“up”) Small # (<1) negative exponent (“down”) “If it was left up to me, I would put it right down” Only include sig figs.
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Scientific Notation Practice Problems
1. 2,400,000 g kg 3. 7 10-5 km 104 mm 2.4 106 g 2.56 10-3 kg km 62,000 mm
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Proportions Direct Proportion y = x y x Inverse Proportion y = 1 x y x
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SI Units Quantity Symbol Base Unit Abbrev Length l meter m Mass m
kilogram kg Time t second s Temp T kelvin K Amount n mole mol
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SI Units Prefix Symbol Factor mega- M 106 kilo- k 103 BASE UNIT ---
100 deci- d 10-1 centi- c 10-2 milli- m 10-3 micro- 10-6 nano- n 10-9 pico- p 10-12
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M V D = Derived Units 1 cm3 = 1 mL 1 dm3 = 1 L
Combination of base units Volume (m3 or cm3) length length length 1 cm3 = 1 mL 1 dm3 = 1 L D = M V Density (kg/m3 or g/cm3) mass per volume
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lecturePLUS Timberlake
Density Density compares the mass of an object to its volume D = mass = g or g volume mL cm3 lecturePLUS Timberlake
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Dimensional Analysis The “Factor-Label” Method
Units, or “labels” are canceled, or “factored” out
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Dimensional Analysis Steps: 1. Identify starting & ending units.
2. Line up conversion factors so units cancel. 3. Multiply all top numbers & divide by each bottom number. 4. Check units & answer.
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Dimensional Analysis Example
You have 1.5 pounds of gold. Find its volume in cm3 if the density of gold is 19.3 g/cm3. lb cm3 1.5 lb 1 kg 2.2 lb 1000 g 1 kg 1 cm3 19.3 g = 35 cm3
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