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Covalent Bonds Electrons are shared
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How do you identify a covalent formula?
All Nonmetals in formula How do you identify a covalent formula?
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Another name for a covalent compound
Molecular compound
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To get the configuration of a noble gas
Why do atoms form bonds?
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Linear Shape of all diatomics?
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Pyramid Shape of NH3, NF3, PH3, etc?
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Bent Shape of H2O, H2S, H2Se, etc.?
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How do you make a Lewis Dot Structure?
Arrange the symbols Count up the valence electrons Distribute the valence electrons, starting with the bonding pairs – single bonds Tests How do you make a Lewis Dot Structure?
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:N:::N: H : H:C:H : H :O::O: : :Cl: :O::C::O: : : : :Cl:C:Cl: : : : H:F: :Cl: :
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Tetrahedral Shape of CH4, CCl4, etc.?
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Has poles – the ends are different!
Polar
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Electron cloud is NOT symmetric. Separation of charge.
Polar
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Electronegativity Difference is 0.5 to 1.7
Polar
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No poles. Ends are the same.
Nonpolar
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Electron cloud is symmetric. No separation of charge.
Nonpolar
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Even, balanced. Symmetrical
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Electronegativity difference = 0 to 0.5
Nonpolar
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Electronegativity difference 1.7
Ionic
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Extremely polar Ionic
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Formula has a metal and a nonmetal
Ionic
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Polar. Water is bent. The O end is a bit negative & the H end is a bit positive.
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Results from attractions between nucleus on 1 atom & electrons on another atom.
Bonding
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releases energy - exothermic
Making a bond …
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Absorbs energy - endothermic
Breaking a bond …
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Covalent Compounds are
Molecular compounds. Covalent Compounds are
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Triple Bond N2
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Double Bond O2
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When bonds are made, energy is …
released. When bonds are made, energy is …
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When bonds are broken, energy is …
absorbed. When bonds are broken, energy is …
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If something exists, it is stable.
Stability
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As the energy of a system , the stability generally …
increases. As the energy of a system , the stability generally …
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As the energy of a system , the stability generally …
decreases. As the energy of a system , the stability generally …
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System releases energy. Its energy level goes down.
Exothermic
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Properties of Molecular Substances
Soft Low melting point & low boiling point Does not conduct electricity in any phase Does not dissolve in water React slowly Properties of Molecular Substances
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Electrons are shared equally between the two atoms
Nonpolar Bonds
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Molecule must contain polar bonds and they must be arranged asymmetrically.
Molecular Polarity
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Molecular Polarity Depends on the shape (Bent & Pyramidal are polar
Linear & tetrahedral, polarity depends on composition.) Molecular Polarity
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Nonpolar Molecules Noble gas atoms (kickballs)
Diatomics of the form A2 (footballs) Larger molecules that have high symmetry Nonpolar Molecules
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Diatomics of the form AB Larger molecules that have low symmetry
Polar Molecules
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Nonpolar Molecules Weak Intermolecular Forces
(Dispersion or Van der Waals) Low boiling points & melting points Tend to be gases Nonpolar Molecules
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Polar Molecules Intermolecular Forces are Dipole-dipole forces
Stick together easier than nonpolar molecules Polar Molecules
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Coordinate Covalent Bond
Covalent bond where both electrons in the bond are donated by 1 atom. Coordinate Covalent Bond
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Coordinate Covalent Bond
+ H H:N:H H:N:H H .. .. + H+ .. .. Coordinate Covalent Bond
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Coordinate Covalent Bond
Both electrons in the bond are donated by the same atom. Coordinate Covalent Bond
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Compound that exhibits both covalent & ionic bonding
Compound that contains a polyatomic ion. Compound that exhibits both covalent & ionic bonding
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How to calculate the polarity of a bond
Subtract the electronegativities of the 2 atoms. How to calculate the polarity of a bond
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Van der Waals forces Or dispersion forces.
Occur between nonpolar molecules. Weakest intermolecular force. Strength increases with size of molecule. Van der Waals forces
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Occurs between polar molecules. Intermediate intermolecular force.
Dipole-dipole forces
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Occurs between molecules containing H-F, H-O, or H-N bonds.
Strongest intermolecular force. Leads to unusually high boiling points. Hydrogen Bonding
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