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Limiting Reagent and Percent Yield
Chemistry Limiting Reagent and Percent Yield
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Limiting and Excess Reagents
An insufficient quantity of any of the reactants will limit the amount of product that forms. Limiting reagent – the reagent that determines the amount of product that can be formed. Excess reagent – the reagent that is not completely used up.
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Determining the Limiting Reagent
For the equation 2Cu(s) + S(s) → Cu2S(s) What is the limiting reagent when 80.0g Cu reacts with 25.0g S? Knowns: Cu = 80g S = 25.0g
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80. 0g Cu x g Cu2S = 100 g Cu2S 128g Cu 160 g Cu2S 25
80.0g Cu x g Cu2S = 100 g Cu2S 128g Cu 160 g Cu2S 25.0g S x g Cu2S = 125 g Cu2S 32 g S 160 g Cu2S With the amounts you have, you can make more Cu2S with the sulfur, so Cu is the limiting reagent.
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Using Limiting Reagent to Find Quantity of a Product
For 2Cu(s) + S(s) → Cu2S(s) What is the maximum number of grams of Cu2S that can be formed when 80.0 g Cu reacts with 25.0g S? Previously determined that Cu is the limiting reagent. Solve for g Cu2S using only the Cu information.
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Percent Yield Theoretical yield – the maximum amount of product that will form during a reaction. Actual yield – the amount of product that actually forms. Percent yield – ratio of actual to theoretical yield. Percent yield = actual yield X 100 theoretical yield
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Calculating Theoretical Yield
For CaCO2(s) → CaO(s) + CO2(g) What is the theoretical yield of CaO if 24.8g CaCO2 is heated? Knowns: CaCO2 = g/mol CaO = 56.1 g/mol 24.8 g CaCO x g CaO = 13.9g CaO 100.1g CaCO g CaO
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Calculating Percent Yield of a Reaction
What is the percent yield if 13.1g CaO is actually produced when 24.8g CaCo3 is heated? Knowns: actual yield =13.1g CaO theoretical yield = 13.9g CaO 13.1g CaO X 100 = 94.2% 13.8g CaO
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Homework - Worksheet
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