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Molecular Shapes Molecules are three dimensional
Electron pairs repel each other Molecular shape adjusts so that e pairs are as far apart as possible Unshared electron pairs distort shapes further because they are more tightly held to one atom
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Molecular Shapes Matter
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What do covalently bonded molecules look like?
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Is Shape Important? Tasting sugars
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C6H12O6 C6H12O6 C6H12O6
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Glucose – 4 models
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Glucose Fructose Lactose Maltose Sucrose
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Steps to Determine Shapes
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Valance Shell Electron Pair Repulsion Theory (VSEPR) or the get away from me Theory!
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Remember the Lone Pairs!!
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# of atoms around central atom # Total e pairs around central atom
Molecular Formula # of atoms around central atom Lone e pairs # Total e pairs around central atom Molecular Shape CH4 4 Tetrahedral NH3 3 1 Pyramidal H2O 2 Bent
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Steps to Determine Molecular Shape
Determine Total Number of valence electrons Determine the central atom Place e pairs between central atom and outside atoms Place remaining electrons around outside atoms ( 2 or 8, depending) The remaining electrons are placed around central atom Determine number of e pairs around central atom Determine number of lone pairs Select correct shape from the table Examine each central-peripheral bond for polarity Decide on the overall molecular polarity
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Remember the Lone Pears!!
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Molecular Forces Intramolecular Forces Intermolecular Forces
Ionic Bonds Metallic Bonds Covalent Bonds Dispersion Forces Dipole Forces Hydrogen Bonds
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