1. Organic Chemistry Chapter 9 Solomons • Fryhle • Snyder
ELEVENTH EDITION
Solomons • Fryhle • Snyder
Chapter 9
Nuclear Magnetic Resonance
and Mass Spectrometry
Copyright © 2014 by John Wiley & Sons, Inc. All rights reserved.

15. n = number of H atoms on carbons next door
Peaks in a signal = n+1 (3 peaks means 2 H next door, 6 peaks means 5 H next door, etc.)

22. Spectrum for compound of the type X-CH2-CH2-CH2-X, where X is electronegative

48. Jab = Jbc

50. Gives two peaks (axial and equatorial) at low temp

52. 13C NMR

55. Proton-decoupled 13C DEPT NMR

61. 1H - 1H COSY NMR

63. Mass Spectrometry

70. Mass Spectrum of CH3F

94. Mass Spectrum for CH4 Showing 13CH4 at m/z 17

96. Mass Spectrum of C6H5Cl showing 35Cl M+ at m/z 112 and 37Cl M+ at m/z 114

97. Notice equal peak heights at m/z 170 and m/z 172 for two isotopes of Br

98. Mass Spectrum of 2-Chloropropane