1. chemistry

2. Reactions in Aqueous Solution
11.3
Reactions in Aqueous Solution
Structures in limestone caverns are formed when carbon dioxide converts calcium hydrogen carbonate into calcium carbonate. The calcium carbonate precipitates and forms dramatic stalactites and stalagmites. You will learn to predict the formation of precipitates and write equations to describe the reactions that produce them.
Illustration from page 342

3. Net Ionic Equations What does a complete ionic equation show?
11.3
Net Ionic Equations
Net Ionic Equations
What does a complete ionic equation show?
What does a net ionic equation show?

4. 11.3
Net Ionic Equations
A complete ionic equation is an equation that shows dissolved ionic compounds as dissociated free ions.
A precipitate of silver chloride forms when aqueous solutions of silver nitrate and sodium chloride are mixed. Inferring Which ions do not participate in the reaction?

5. 11.3
Net Ionic Equations
An ion that appears on both sides of an equation and is not directly involved in the reaction is called a spectator ion.
The net ionic equation is an equation for a reaction in solution that shows only those particles that are directly involved in the chemical change i.e the spectator ions are removed.

6. 11.3
Net Ionic Equations
A net ionic equation shows only those particles involved in the reaction and is balanced with respect to both mass and charge.

7. 11.3
Net Ionic Equations
Sodium ions and nitrate ions are not changed during the chemical reaction of silver nitrate and sodium chloride so the net ionic equation is
Equation from text page 343

9. for Conceptual Problem 11.9
Problem Solving Solve Problem 28 with the help of an interactive guided tutorial.
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10. Predicting the Formation of a Precipitate
11.3
Predicting the Formation of a Precipitate
Predicting the Formation of a Precipitate
How can you predict the formation of a precipitate in a double-replacement reaction?

11. Predicting the Formation of a Precipitate
11.3
Predicting the Formation of a Precipitate
You can predict the formation of a precipitate by using the general rules for solubility of ionic compounds.

12. Predicting the Formation of a Precipitate
11.3
Predicting the Formation of a Precipitate

13. Predicting the Formation of a Precipitate
11.3
Predicting the Formation of a Precipitate
Will a precipitate form when a sodium carbonate solution is mixed with a barium nitrate solution?
Equation from text page 344

14. Predicting the Formation of a Precipitate
11.3
Predicting the Formation of a Precipitate
Sodium nitrate is soluble but barium carbonate is insoluble. The net ionic equation is

15. 11.3 Section Quiz.
11.3.

16. 11.3 Section Quiz.
1. Identify the correct net ionic equation for the following reaction and the spectator ion, if there is one.
FeO(s) + 2HClO4(aq)  H2O(l) + Fe(ClO4)2(aq)
FeO(s) + 2H+(aq) + 2ClO4-(aq)  H2O(l) + Fe2+(aq) + 2ClO4-(aq); no spectator ion
FeO(s) + 2H+(aq) + 2ClO4-(aq)  H2O(l) + Fe2+(aq) + 2ClO4-(aq); ClO4- is a spectator ion
FeO(s) + 2H+(aq)  H2O(l) + Fe2+(aq); ClO4-
FeO(s) + 2HClO4(aq)  H2O(l) + Fe(ClO4)2(aq); no spectator ion

17. 11.3 Section Quiz.
2. Which one of the following products of double- replacement reactions would NOT form a precipitate?
AgCl
PbSO4
Mg(OH)2
Mo(NO3)2

18. 11.3 Section Quiz
3. Which reaction will NOT produce a precipitate from aqueous solution?
Hg2(NO3)2 + KCl
FeSO4 + Ba(OH)2
Pb(NO3)2 + Na2CO3
NaBr + Al2(SO4)3

19. END OF SHOW