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Ocean Chemistry
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Forschammer - Law of Constant Proportions
Ratio of ions Na+ : Cl- : SO4-- : Mg++: K+ : Ca++ :CO3-- Constant - worldwide Calculation of salinity from chlorinity chlorinity - wt. of Cl-, Br-, I- ions Salinity % = x chlorinity
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Residence time = AMOUNT OF ELEMENT IN OCEAN
Residence time = AMOUNT OF ELEMENT IN OCEAN RATE OF ADDITION OR REMOVAL Cl x 106 yrs Na x 106 yrs Mg(++) 13 x 106 yrs Carbonate 110 x 103 Iron 200
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Cycling of Sea Salt Volcanic activity Sediments uplifted
H2S Rainfall Volcanic activity Cl- SO4-2 Sediments uplifted River discharge & runoff Ca+2 K+ Mg+2 CO3-2 Ca+2 SO4-2 Mg+2 N+ Organisms die adsorbed by clays Leaching from rocks precipitation Bottom sediments
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Importance of CO3-- CO3--
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